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Synthesis, Characterization, and Thermal Decomposition of [Cl2GaP(SiMe3)2]2, a Potential Precursor to Gallium Phosphide

Publication ,  Journal Article
Wells, RL; Self, MF; McPhail, AT; Aubuchon, SR; Woudenberg, RC; Jasinski, JP
Published in: Organometallics
January 1, 1993
Published version (DOI)

[Cl2GaP(SiMe3)2]2 (1) has been prepared from the 1:1 reaction of GaCl3 with P(SiMe3)3. Thermal decomposition of 1 produces a brown powder which contains GaP, as evidenced by an X-ray powder pattern and partial elemental analysis. Compound 1 crystallizes in the monoclinic space group P21/n (No. 14) with a = 9.754(2) Å, b = 15.585(5) Å, c = 9.839(2) Å, and β = 96.18(1)°, is composed of a planar [formula omitted], with GaP bond distances of 2.378(2) and 2.380(2) Å, and contains exocyclic chlorine and SiMe3 ligands. The ring core is a slightly distorted square, with GaPGa′ and PGaP′ bond angles of 86.41(7) and 93.59(7)°, respectively. Additionally, 1H NMR confirms that 1 exhibits monomer—dimer equilibrium in solution. © 1993, American Chemical Society. All rights reserved.

Duke Scholars

Andrew T. McPhail
Author Andrew T. McPhail Chemistry
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Published In

Organometallics

DOI

10.1021/om00031a061

EISSN

1520-6041

ISSN

0276-7333

Publication Date

January 1, 1993

Volume

12

Issue

7

Start / End Page

2832 / 2834

Related Subject Headings

  • Organic Chemistry
  • 3406 Physical chemistry
  • 3402 Inorganic chemistry
  • 0399 Other Chemical Sciences
  • 0305 Organic Chemistry
  • 0302 Inorganic Chemistry
 

Citation

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Wells, R. L., Self, M. F., McPhail, A. T., Aubuchon, S. R., Woudenberg, R. C., & Jasinski, J. P. (1993). Synthesis, Characterization, and Thermal Decomposition of [Cl2GaP(SiMe3)2]2, a Potential Precursor to Gallium Phosphide. Organometallics, 12(7), 2832–2834. https://doi.org/10.1021/om00031a061
Wells, R. L., M. F. Self, A. T. McPhail, S. R. Aubuchon, R. C. Woudenberg, and J. P. Jasinski. “Synthesis, Characterization, and Thermal Decomposition of [Cl2GaP(SiMe3)2]2, a Potential Precursor to Gallium Phosphide.” Organometallics 12, no. 7 (January 1, 1993): 2832–34. https://doi.org/10.1021/om00031a061.
Wells RL, Self MF, McPhail AT, Aubuchon SR, Woudenberg RC, Jasinski JP. Synthesis, Characterization, and Thermal Decomposition of [Cl2GaP(SiMe3)2]2, a Potential Precursor to Gallium Phosphide. Organometallics. 1993 Jan 1;12(7):2832–4.
Wells, R. L., et al. “Synthesis, Characterization, and Thermal Decomposition of [Cl2GaP(SiMe3)2]2, a Potential Precursor to Gallium Phosphide.” Organometallics, vol. 12, no. 7, Jan. 1993, pp. 2832–34. Scopus, doi:10.1021/om00031a061.
Wells RL, Self MF, McPhail AT, Aubuchon SR, Woudenberg RC, Jasinski JP. Synthesis, Characterization, and Thermal Decomposition of [Cl2GaP(SiMe3)2]2, a Potential Precursor to Gallium Phosphide. Organometallics. 1993 Jan 1;12(7):2832–2834.
Journal cover image

Published In

Organometallics

DOI

10.1021/om00031a061

EISSN

1520-6041

ISSN

0276-7333

Publication Date

January 1, 1993

Volume

12

Issue

7

Start / End Page

2832 / 2834

Related Subject Headings

  • Organic Chemistry
  • 3406 Physical chemistry
  • 3402 Inorganic chemistry
  • 0399 Other Chemical Sciences
  • 0305 Organic Chemistry
  • 0302 Inorganic Chemistry