Preparation and X-ray crystal structure study of a polypyridyl ruthenium(II) complex containing a dehydrodithizone ligand
Publication
, Journal Article
Walsh, JL; McCracken, R; McPhail, AT
Published in: Polyhedron
August 31, 1998
Coordination of 2,3-diphenyltetrazolium-5-thiolate (tet) to an Ru(trpy)(bpy)(OH2)2 (trpy=2,2′:6′,2″-terpyridine; bpy=2,2′-bipyridine) centre resulted in the formation of [Ru(trpy)(bpy) (tet)](ClO4)2. Single-crystal X-ray analysis revealed that the tet ligand is bound through the sulfur atom to a somewhat distorted-octahedral ruthenium centre. The Ru-S bond distance is 2.393(2) Å, and the Ru-S-C bond angle is 115.1(2)°; the tet N-N bonded distances [1.306(10) Å-1.316(9) Å] are essentially equal. These data, as well as spectroscopic and electrochemical evidence, suggest that the tetrazolium ring exhibits delocalized, mesoionic character with some thiolate character on the sulfur atom.
Duke Scholars
Published In
Polyhedron
DOI
ISSN
0277-5387
Publication Date
August 31, 1998
Volume
17
Issue
18
Start / End Page
3221 / 3226
Related Subject Headings
- Inorganic & Nuclear Chemistry
- 3403 Macromolecular and materials chemistry
- 3402 Inorganic chemistry
- 0399 Other Chemical Sciences
- 0306 Physical Chemistry (incl. Structural)
- 0302 Inorganic Chemistry
Citation
APA
Chicago
ICMJE
MLA
NLM
Walsh, J. L., McCracken, R., & McPhail, A. T. (1998). Preparation and X-ray crystal structure study of a polypyridyl ruthenium(II) complex containing a dehydrodithizone ligand. Polyhedron, 17(18), 3221–3226. https://doi.org/10.1016/S0277-5387(98)00095-3
Walsh, J. L., R. McCracken, and A. T. McPhail. “Preparation and X-ray crystal structure study of a polypyridyl ruthenium(II) complex containing a dehydrodithizone ligand.” Polyhedron 17, no. 18 (August 31, 1998): 3221–26. https://doi.org/10.1016/S0277-5387(98)00095-3.
Walsh JL, McCracken R, McPhail AT. Preparation and X-ray crystal structure study of a polypyridyl ruthenium(II) complex containing a dehydrodithizone ligand. Polyhedron. 1998 Aug 31;17(18):3221–6.
Walsh, J. L., et al. “Preparation and X-ray crystal structure study of a polypyridyl ruthenium(II) complex containing a dehydrodithizone ligand.” Polyhedron, vol. 17, no. 18, Aug. 1998, pp. 3221–26. Scopus, doi:10.1016/S0277-5387(98)00095-3.
Walsh JL, McCracken R, McPhail AT. Preparation and X-ray crystal structure study of a polypyridyl ruthenium(II) complex containing a dehydrodithizone ligand. Polyhedron. 1998 Aug 31;17(18):3221–3226.
Published In
Polyhedron
DOI
ISSN
0277-5387
Publication Date
August 31, 1998
Volume
17
Issue
18
Start / End Page
3221 / 3226
Related Subject Headings
- Inorganic & Nuclear Chemistry
- 3403 Macromolecular and materials chemistry
- 3402 Inorganic chemistry
- 0399 Other Chemical Sciences
- 0306 Physical Chemistry (incl. Structural)
- 0302 Inorganic Chemistry