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Static secondary ion mass spectrometry of organic plasma‐deposited films created from stable isotope‐labeled precursors. II. Mixtures of acetone and oxygen

Publication ,  Journal Article
Chilkoti, A; Ratner, BD; Briggs, D; Reich, F
Published in: Journal of Polymer Science Part A: Polymer Chemistry
January 1, 1992

A series of plasma‐deposited films (PDFs), created by blending controlled ratios of acetone vapor and oxygen in the feed to the plasma reactor, were analyzed by static secondary ion mass spectrometry (SIMS). Examination of the quadrupole‐based static SIMS fragmentation patterns of acetone–O2 PDFs created from 13C‐labeled acetone generally allowed the hydrocarbon secondary ions to be distinguished from oxygen‐containing secondary ions. These results were compared with those obtained via high‐mass resolution time‐of‐flight (TOF)‐SIMS. The identified secondary ions were then assigned structural attributes, based on comparison of the static SIMS spectra of the acetone–O2 PDFs with those of conventional hydrocarbon and oxygen‐containing polymers. A preliminary investigation to unravel the mechanism of oxygen incorporation in the acetone–O2 PDFs from the two plasma feed components was undertaken through the analysis of PDFs created from 1,2,313C3‐acetone(16O) vapor and 18O2 gas. Copyright © 1992 John Wiley & Sons, Inc.

Duke Scholars

Published In

Journal of Polymer Science Part A: Polymer Chemistry

DOI

EISSN

1099-0518

ISSN

0887-624X

Publication Date

January 1, 1992

Volume

30

Issue

7

Start / End Page

1261 / 1278

Related Subject Headings

  • Polymers
  • 3406 Physical chemistry
  • 3403 Macromolecular and materials chemistry
  • 0912 Materials Engineering
  • 0306 Physical Chemistry (incl. Structural)
  • 0303 Macromolecular and Materials Chemistry
 

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Chilkoti, A., Ratner, B. D., Briggs, D., & Reich, F. (1992). Static secondary ion mass spectrometry of organic plasma‐deposited films created from stable isotope‐labeled precursors. II. Mixtures of acetone and oxygen. Journal of Polymer Science Part A: Polymer Chemistry, 30(7), 1261–1278. https://doi.org/10.1002/pola.1992.080300704
Chilkoti, A., B. D. Ratner, D. Briggs, and F. Reich. “Static secondary ion mass spectrometry of organic plasma‐deposited films created from stable isotope‐labeled precursors. II. Mixtures of acetone and oxygen.” Journal of Polymer Science Part A: Polymer Chemistry 30, no. 7 (January 1, 1992): 1261–78. https://doi.org/10.1002/pola.1992.080300704.
Chilkoti A, Ratner BD, Briggs D, Reich F. Static secondary ion mass spectrometry of organic plasma‐deposited films created from stable isotope‐labeled precursors. II. Mixtures of acetone and oxygen. Journal of Polymer Science Part A: Polymer Chemistry. 1992 Jan 1;30(7):1261–78.
Chilkoti, A., et al. “Static secondary ion mass spectrometry of organic plasma‐deposited films created from stable isotope‐labeled precursors. II. Mixtures of acetone and oxygen.” Journal of Polymer Science Part A: Polymer Chemistry, vol. 30, no. 7, Jan. 1992, pp. 1261–78. Scopus, doi:10.1002/pola.1992.080300704.
Chilkoti A, Ratner BD, Briggs D, Reich F. Static secondary ion mass spectrometry of organic plasma‐deposited films created from stable isotope‐labeled precursors. II. Mixtures of acetone and oxygen. Journal of Polymer Science Part A: Polymer Chemistry. 1992 Jan 1;30(7):1261–1278.
Journal cover image

Published In

Journal of Polymer Science Part A: Polymer Chemistry

DOI

EISSN

1099-0518

ISSN

0887-624X

Publication Date

January 1, 1992

Volume

30

Issue

7

Start / End Page

1261 / 1278

Related Subject Headings

  • Polymers
  • 3406 Physical chemistry
  • 3403 Macromolecular and materials chemistry
  • 0912 Materials Engineering
  • 0306 Physical Chemistry (incl. Structural)
  • 0303 Macromolecular and Materials Chemistry