n-paraffin solid solutions: modification of phase separation with carbon number
Publication
, Journal Article
Gilbert, EP; Reynolds, PA; Brown, AS; White, JW
Published in: Chem. Phys. Lett. (Netherlands)
1996
Small-angle neutron scattering is used to monitor microphase formation in the solid state in equimolar binary hydrocarbon systems CnH2n+2:CmD2m+2 for selected n=20-34 and m=36. Microphase formation is maximum for n=28 and negligible for n=20, 32 and 34. n=30 is found to be intermediate. These observations are explicable in terms of increasing molar volume differences between the two components forming the mixture. As the chain length difference increases, the formation of a lamellar microphase occurs in preference to a continuous solid solution until this is itself overtaken by two-phase separation
Duke Scholars
Published In
Chem. Phys. Lett. (Netherlands)
DOI
Publication Date
1996
Volume
255
Issue
4-6
Start / End Page
373 / 377
Related Subject Headings
- Chemical Physics
- 10 Technology
- 03 Chemical Sciences
- 02 Physical Sciences
Citation
APA
Chicago
ICMJE
MLA
NLM
Gilbert, E. P., Reynolds, P. A., Brown, A. S., & White, J. W. (1996). n-paraffin solid solutions: modification of phase separation with carbon number. Chem. Phys. Lett. (Netherlands), 255(4–6), 373–377. https://doi.org/10.1016/0009-2614(96)00371-5
Gilbert, E. P., P. A. Reynolds, A. S. Brown, and J. W. White. “n-paraffin solid solutions: modification of phase separation with carbon number.” Chem. Phys. Lett. (Netherlands) 255, no. 4–6 (1996): 373–77. https://doi.org/10.1016/0009-2614(96)00371-5.
Gilbert EP, Reynolds PA, Brown AS, White JW. n-paraffin solid solutions: modification of phase separation with carbon number. Chem Phys Lett (Netherlands). 1996;255(4–6):373–7.
Gilbert, E. P., et al. “n-paraffin solid solutions: modification of phase separation with carbon number.” Chem. Phys. Lett. (Netherlands), vol. 255, no. 4–6, 1996, pp. 373–77. Manual, doi:10.1016/0009-2614(96)00371-5.
Gilbert EP, Reynolds PA, Brown AS, White JW. n-paraffin solid solutions: modification of phase separation with carbon number. Chem Phys Lett (Netherlands). 1996;255(4–6):373–377.
Published In
Chem. Phys. Lett. (Netherlands)
DOI
Publication Date
1996
Volume
255
Issue
4-6
Start / End Page
373 / 377
Related Subject Headings
- Chemical Physics
- 10 Technology
- 03 Chemical Sciences
- 02 Physical Sciences