Intermolecular hydroamination of allenes with N-unsubstituted carbamates catalyzed by a gold(I) N-heterocyclic carbene complex.
Publication
, Journal Article
Kinder, RE; Zhang, Z; Widenhoefer, RA
Published in: Organic letters
July 2008
Reaction of 2,3-pentadienyl benzoate with benzyl carbamate catalyzed by a 1:1 mixture of (NHC)AuCl and AgOTf in dioxane at 23 degrees C for 5 h led to isolation of (E)-4-(benzyloxycarbonylamino)-2-pentenyl benzoate in 84% yield as a single regio- and diastereomer. Gold(I)-catalyzed hydroamination was effective for a number of N-unsubstituted carbamates and a range of substituted allenes.
Duke Scholars
Published In
Organic letters
DOI
EISSN
1523-7052
ISSN
1523-7060
Publication Date
July 2008
Volume
10
Issue
14
Start / End Page
3157 / 3159
Related Subject Headings
- Stereoisomerism
- Organogold Compounds
- Organic Chemistry
- Molecular Structure
- Methane
- Combinatorial Chemistry Techniques
- Catalysis
- Carbamates
- Benzoates
- Alkadienes
Citation
APA
Chicago
ICMJE
MLA
NLM
Kinder, R. E., Zhang, Z., & Widenhoefer, R. A. (2008). Intermolecular hydroamination of allenes with N-unsubstituted carbamates catalyzed by a gold(I) N-heterocyclic carbene complex. Organic Letters, 10(14), 3157–3159. https://doi.org/10.1021/ol8010858
Kinder, Robert E., Zhibin Zhang, and Ross A. Widenhoefer. “Intermolecular hydroamination of allenes with N-unsubstituted carbamates catalyzed by a gold(I) N-heterocyclic carbene complex.” Organic Letters 10, no. 14 (July 2008): 3157–59. https://doi.org/10.1021/ol8010858.
Kinder RE, Zhang Z, Widenhoefer RA. Intermolecular hydroamination of allenes with N-unsubstituted carbamates catalyzed by a gold(I) N-heterocyclic carbene complex. Organic letters. 2008 Jul;10(14):3157–9.
Kinder, Robert E., et al. “Intermolecular hydroamination of allenes with N-unsubstituted carbamates catalyzed by a gold(I) N-heterocyclic carbene complex.” Organic Letters, vol. 10, no. 14, July 2008, pp. 3157–59. Epmc, doi:10.1021/ol8010858.
Kinder RE, Zhang Z, Widenhoefer RA. Intermolecular hydroamination of allenes with N-unsubstituted carbamates catalyzed by a gold(I) N-heterocyclic carbene complex. Organic letters. 2008 Jul;10(14):3157–3159.
Published In
Organic letters
DOI
EISSN
1523-7052
ISSN
1523-7060
Publication Date
July 2008
Volume
10
Issue
14
Start / End Page
3157 / 3159
Related Subject Headings
- Stereoisomerism
- Organogold Compounds
- Organic Chemistry
- Molecular Structure
- Methane
- Combinatorial Chemistry Techniques
- Catalysis
- Carbamates
- Benzoates
- Alkadienes