Scaling Laws in Supramolecular Polymer Networks.
Publication
, Journal Article
Xu, D; Craig, SL
Published in: Macromolecules
January 2011
The linear rheological properties of networks formed by adding bis-Pd(II) cross-linkers to poly(4-vinylpyridine) (PVP) solution are examined, and the scaling law relationships between the zero shear viscosity (η(0)) of the networks versus the concentration of PVP solution (C(PVP)), the concentration of cross-linkers (C(X)), and the number density of elastically active chains (v(phantom)) are experimentally determined. The scaling law relationships are compared to the theoretical expectations of the Sticky Rouse and Sticky Reptation models (Macromolecules2001, 34, 1058-1068), and both qualitative and quantitative differences are observed.
Duke Scholars
Published In
Macromolecules
DOI
EISSN
1520-5835
ISSN
0024-9297
Publication Date
January 2011
Volume
44
Issue
13
Start / End Page
5465 / 5472
Related Subject Headings
- Polymers
- 40 Engineering
- 34 Chemical sciences
- 09 Engineering
- 03 Chemical Sciences
Citation
APA
Chicago
ICMJE
MLA
NLM
Xu, D., & Craig, S. L. (2011). Scaling Laws in Supramolecular Polymer Networks. Macromolecules, 44(13), 5465–5472. https://doi.org/10.1021/ma200096s
Xu, Donghua, and Stephen L. Craig. “Scaling Laws in Supramolecular Polymer Networks.” Macromolecules 44, no. 13 (January 2011): 5465–72. https://doi.org/10.1021/ma200096s.
Xu D, Craig SL. Scaling Laws in Supramolecular Polymer Networks. Macromolecules. 2011 Jan;44(13):5465–72.
Xu, Donghua, and Stephen L. Craig. “Scaling Laws in Supramolecular Polymer Networks.” Macromolecules, vol. 44, no. 13, Jan. 2011, pp. 5465–72. Epmc, doi:10.1021/ma200096s.
Xu D, Craig SL. Scaling Laws in Supramolecular Polymer Networks. Macromolecules. 2011 Jan;44(13):5465–5472.
Published In
Macromolecules
DOI
EISSN
1520-5835
ISSN
0024-9297
Publication Date
January 2011
Volume
44
Issue
13
Start / End Page
5465 / 5472
Related Subject Headings
- Polymers
- 40 Engineering
- 34 Chemical sciences
- 09 Engineering
- 03 Chemical Sciences