Scholars@Duke publication: Branching ratios in activated systems

Branching ratios in activated systems

Journal articles - Journal Article

Craig, SL; Zhong, M; Choo, B; Brauman, JI

Published in: Journal of Physical Chemistry A

January 2, 1997

Branching between reaction channels in activated systems is often observed to vary with changes in the potential energy surface as Δln(k1/k2) ∝ Δ(ΔE‡1 - ΔE‡2). RRKM calculations demonstrate that in many, but not all, cases the log-linear relationship accurately describes branching in nonthermal distributions of reactants with energies well above the threshold for reaction. The origin of this relationship and conditions necessary for its validity can be understood in terms of quantum RRK theory.

Duke Scholars

Author Stephen L Craig Chemistry

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Published In

Journal of Physical Chemistry A

DOI

10.1021/jp961665j

ISSN

1089-5639

Publication Date

January 2, 1997

Volume

101

Issue

Start / End Page

19 / 24

Related Subject Headings

5102 Atomic, molecular and optical physics
3407 Theoretical and computational chemistry
3406 Physical chemistry

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Craig, S. L., Zhong, M., Choo, B., & Brauman, J. I. (1997). Branching ratios in activated systems. Journal of Physical Chemistry A, 101(1), 19–24. https://doi.org/10.1021/jp961665j

Craig, S. L., M. Zhong, B. Choo, and J. I. Brauman. “Branching ratios in activated systems.” Journal of Physical Chemistry A 101, no. 1 (January 2, 1997): 19–24. https://doi.org/10.1021/jp961665j.

Craig SL, Zhong M, Choo B, Brauman JI. Branching ratios in activated systems. Journal of Physical Chemistry A. 1997 Jan 2;101(1):19–24.

Craig, S. L., et al. “Branching ratios in activated systems.” Journal of Physical Chemistry A, vol. 101, no. 1, Jan. 1997, pp. 19–24. Scopus, doi:10.1021/jp961665j.

Craig SL, Zhong M, Choo B, Brauman JI. Branching ratios in activated systems. Journal of Physical Chemistry A. 1997 Jan 2;101(1):19–24.

Published In

Journal of Physical Chemistry A

DOI

10.1021/jp961665j

ISSN

1089-5639

Publication Date

January 2, 1997

Volume

101

Issue

Start / End Page

19 / 24

Related Subject Headings

5102 Atomic, molecular and optical physics
3407 Theoretical and computational chemistry
3406 Physical chemistry