Scholars@Duke
Journal cover image

Plasma polymerization of iron pentacarbonyl with C2 hydrocarbons

Publication ,  Journal Article
Morosoff, N; Patel, DL; White, AR; Umaña, M; Crumbliss, AL; Lugg, PS; Brown, DB
Published in: Thin Solid Films
July 6, 1984
Published version (DOI)

Iron-containing plasma polymers are deposited from a plasma using iron pentacarbonyl (Fe(CO)5) plus C2 hydrocarbons as comonomers and are characterized using a variety of techniques. The plasma polymers are found to contain high proportions of highly dispersed iron oxide as well as lesser quantities of carboxylate and/or ketonate ions and aldehydic and/or ketonic groups. By decreasing the energy per unit mass W/FM part of the iron is deposited in a lower oxidation state complexed to CO and is soluble in organic solvents. The effects of hydrocarbon saturation and of the ratio of hydrocarbon to Fe(CO)5 are also described and a comparison is made with the product deposited when only Fe(CO)5 (or Fe(CO)5 plus H2) is used as the monomer. © 1984.

Duke Scholars

Alvin L. Crumbliss
Author Alvin L. Crumbliss Chemistry

Published In

Thin Solid Films

DOI

10.1016/0040-6090(84)90191-3

ISSN

0040-6090

Publication Date

July 6, 1984

Volume

117

Issue

1

Start / End Page

33 / 58

Related Subject Headings

  • Applied Physics
  • 51 Physical sciences
  • 40 Engineering
  • 10 Technology
  • 09 Engineering
  • 02 Physical Sciences
 

Citation

APA
Chicago
ICMJE
MLA
NLM
Morosoff, N., Patel, D. L., White, A. R., Umaña, M., Crumbliss, A. L., Lugg, P. S., & Brown, D. B. (1984). Plasma polymerization of iron pentacarbonyl with C2 hydrocarbons. Thin Solid Films, 117(1), 33–58. https://doi.org/10.1016/0040-6090(84)90191-3
Morosoff, N., D. L. Patel, A. R. White, M. Umaña, A. L. Crumbliss, P. S. Lugg, and D. B. Brown. “Plasma polymerization of iron pentacarbonyl with C2 hydrocarbons.” Thin Solid Films 117, no. 1 (July 6, 1984): 33–58. https://doi.org/10.1016/0040-6090(84)90191-3.
Morosoff N, Patel DL, White AR, Umaña M, Crumbliss AL, Lugg PS, et al. Plasma polymerization of iron pentacarbonyl with C2 hydrocarbons. Thin Solid Films. 1984 Jul 6;117(1):33–58.
Morosoff, N., et al. “Plasma polymerization of iron pentacarbonyl with C2 hydrocarbons.” Thin Solid Films, vol. 117, no. 1, July 1984, pp. 33–58. Scopus, doi:10.1016/0040-6090(84)90191-3.
Morosoff N, Patel DL, White AR, Umaña M, Crumbliss AL, Lugg PS, Brown DB. Plasma polymerization of iron pentacarbonyl with C2 hydrocarbons. Thin Solid Films. 1984 Jul 6;117(1):33–58.
Journal cover image

Published In

Thin Solid Films

DOI

10.1016/0040-6090(84)90191-3

ISSN

0040-6090

Publication Date

July 6, 1984

Volume

117

Issue

1

Start / End Page

33 / 58

Related Subject Headings

  • Applied Physics
  • 51 Physical sciences
  • 40 Engineering
  • 10 Technology
  • 09 Engineering
  • 02 Physical Sciences