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Depolarized Rayleigh scattering study of pyrimidine

Publication ,  Journal Article
Whittenburg, SL; Jain, VK; McKinnon, SJ
Published in: Journal of Molecular Liquids
January 1, 1990

The depolarized Rayleigh spectrum from pyrimidine has been obtained from 296K to 395K. The spectra do not display a shear wave dip at zero frequency due to translation-rotation coupling. The Stokes - Einstein - Debye plot of the reorientation time versus viscosity/temperature displays a slightly non-linear relation. The light scattering orientation pair correlation factor obtained by comparing the depolarized Rayleigh reorientation to the single particle time from NMR for pyrimidine is 2.3. This value is compared to other azobenzenes. © 1990.

Duke Scholars

Published In

Journal of Molecular Liquids

DOI

ISSN

0167-7322

Publication Date

January 1, 1990

Volume

47

Issue

1-3

Start / End Page

161 / 169

Related Subject Headings

  • Chemical Physics
  • 4004 Chemical engineering
  • 3406 Physical chemistry
  • 0306 Physical Chemistry (incl. Structural)
 

Citation

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Whittenburg, S. L., Jain, V. K., & McKinnon, S. J. (1990). Depolarized Rayleigh scattering study of pyrimidine. Journal of Molecular Liquids, 47(1–3), 161–169. https://doi.org/10.1016/0167-7322(90)80073-S
Whittenburg, S. L., V. K. Jain, and S. J. McKinnon. “Depolarized Rayleigh scattering study of pyrimidine.” Journal of Molecular Liquids 47, no. 1–3 (January 1, 1990): 161–69. https://doi.org/10.1016/0167-7322(90)80073-S.
Whittenburg SL, Jain VK, McKinnon SJ. Depolarized Rayleigh scattering study of pyrimidine. Journal of Molecular Liquids. 1990 Jan 1;47(1–3):161–9.
Whittenburg, S. L., et al. “Depolarized Rayleigh scattering study of pyrimidine.” Journal of Molecular Liquids, vol. 47, no. 1–3, Jan. 1990, pp. 161–69. Scopus, doi:10.1016/0167-7322(90)80073-S.
Whittenburg SL, Jain VK, McKinnon SJ. Depolarized Rayleigh scattering study of pyrimidine. Journal of Molecular Liquids. 1990 Jan 1;47(1–3):161–169.
Journal cover image

Published In

Journal of Molecular Liquids

DOI

ISSN

0167-7322

Publication Date

January 1, 1990

Volume

47

Issue

1-3

Start / End Page

161 / 169

Related Subject Headings

  • Chemical Physics
  • 4004 Chemical engineering
  • 3406 Physical chemistry
  • 0306 Physical Chemistry (incl. Structural)