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Depolarized Rayleigh scattering study of neat formamide

Publication ,  Journal Article
Whittenburg, SL; Jain, VK; McKinnon, SJ
Published in: Journal of Physical Chemistry
January 1, 1986
Published version (DOI)

The depolarized Rayleigh spectrum of formamide has been measured as a function of temperature. The spectrum of neat formamide indicates that the static orientation pair correlation factor, g2, is large compared to other small molecular fluids. The experimental slope of τRay plotted vs. ηs/Τ is found to be close to the theoretical slope obtained by assuming slip boundary conditions. Within the experimental error a nonzero intercept is also found. The depolarized Rayleigh spectrum may also reflect translation-rotation coupling if the reorientational motion couples to the shear wave. The shear wave dip in the Lorentzian peak is not wide enough to be resolved in neat formamide. © 1986 American Chemical Society.

Duke Scholars

Stuart James McKinnon
Author Stuart James McKinnon Ophthalmology, Glaucoma

Published In

Journal of Physical Chemistry

DOI

10.1021/j100278a008

ISSN

0022-3654

Publication Date

January 1, 1986

Volume

90

Issue

6

Start / End Page

1004 / 1005
 

Citation

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ICMJE
MLA
NLM
Whittenburg, S. L., Jain, V. K., & McKinnon, S. J. (1986). Depolarized Rayleigh scattering study of neat formamide. Journal of Physical Chemistry, 90(6), 1004–1005. https://doi.org/10.1021/j100278a008
Whittenburg, S. L., V. K. Jain, and S. J. McKinnon. “Depolarized Rayleigh scattering study of neat formamide.” Journal of Physical Chemistry 90, no. 6 (January 1, 1986): 1004–5. https://doi.org/10.1021/j100278a008.
Whittenburg SL, Jain VK, McKinnon SJ. Depolarized Rayleigh scattering study of neat formamide. Journal of Physical Chemistry. 1986 Jan 1;90(6):1004–5.
Whittenburg, S. L., et al. “Depolarized Rayleigh scattering study of neat formamide.” Journal of Physical Chemistry, vol. 90, no. 6, Jan. 1986, pp. 1004–05. Scopus, doi:10.1021/j100278a008.
Whittenburg SL, Jain VK, McKinnon SJ. Depolarized Rayleigh scattering study of neat formamide. Journal of Physical Chemistry. 1986 Jan 1;90(6):1004–1005.

Published In

Journal of Physical Chemistry

DOI

10.1021/j100278a008

ISSN

0022-3654

Publication Date

January 1, 1986

Volume

90

Issue

6

Start / End Page

1004 / 1005