The fragmentation of stereoisomeric androstanediol t‐butyldimethylsilyl ethers. A study by linked field scanning
Publication
, Journal Article
Gaskell, SJ; Pike, AW; Millington, DS
Published in: Biological Mass Spectrometry
January 1, 1979
The major fragmentation pathways of eight isomeric androstane‐3,17‐diols, as their bis‐t‐butyldimethylsilyl ethers, were elucidated by linked scanning of the magnetic and electric fields in a double focusing mass spectrometer. Four competing pathways were observed, each characterized by losses of alkylsilanol moieties from a common [M–C4H9]+ precursor. Pronounced differences in the spectra obtained by linked scans complement the coventional mas spectra in the differentiation of the isomeric structures. Copyright © 1979 Heyden & Son Ltd
Duke Scholars
Published In
Biological Mass Spectrometry
DOI
EISSN
1096-9888
ISSN
0306-042X
Publication Date
January 1, 1979
Volume
6
Issue
2
Start / End Page
78 / 81
Citation
APA
Chicago
ICMJE
MLA
NLM
Gaskell, S. J., Pike, A. W., & Millington, D. S. (1979). The fragmentation of stereoisomeric androstanediol t‐butyldimethylsilyl ethers. A study by linked field scanning. Biological Mass Spectrometry, 6(2), 78–81. https://doi.org/10.1002/bms.1200060208
Gaskell, S. J., A. W. Pike, and D. S. Millington. “The fragmentation of stereoisomeric androstanediol t‐butyldimethylsilyl ethers. A study by linked field scanning.” Biological Mass Spectrometry 6, no. 2 (January 1, 1979): 78–81. https://doi.org/10.1002/bms.1200060208.
Gaskell SJ, Pike AW, Millington DS. The fragmentation of stereoisomeric androstanediol t‐butyldimethylsilyl ethers. A study by linked field scanning. Biological Mass Spectrometry. 1979 Jan 1;6(2):78–81.
Gaskell, S. J., et al. “The fragmentation of stereoisomeric androstanediol t‐butyldimethylsilyl ethers. A study by linked field scanning.” Biological Mass Spectrometry, vol. 6, no. 2, Jan. 1979, pp. 78–81. Scopus, doi:10.1002/bms.1200060208.
Gaskell SJ, Pike AW, Millington DS. The fragmentation of stereoisomeric androstanediol t‐butyldimethylsilyl ethers. A study by linked field scanning. Biological Mass Spectrometry. 1979 Jan 1;6(2):78–81.
Published In
Biological Mass Spectrometry
DOI
EISSN
1096-9888
ISSN
0306-042X
Publication Date
January 1, 1979
Volume
6
Issue
2
Start / End Page
78 / 81