The Reaction between Sulfur Dioxide and Hexamethyldisilazane. 2. Oxygen Atom Transfer from Sulfur Dioxide
Publication
, Journal Article
Bennett, DW; Spicer, LD
Published in: Inorganic Chemistry
January 1, 1982
The new reaction between sulfur dioxide and hexamethyldisilazane, which forms ((CH3)3Si)2O, (CH3)3SiNSO, and NH4(CH3)3SiOSO2, is characterized. In this reaction oxygen is transferred to silicon and sulfur from sulfur dioxide, but Si-N bonding is still partially retained. The solid product, ammonium trimethylsilyl sulfite, sublimes readily at ambient temperature but exhibits ionic properties. The variety of products and the overall reaction stoichiometry impose severe restrictions on possible reaction mechanisms. These constraints are discussed, and a consistent reaction scheme is proposed for this facile but unusual reaction. © 1982, American Chemical Society. All rights reserved.
Duke Scholars
Published In
Inorganic Chemistry
DOI
EISSN
1520-510X
ISSN
0020-1669
Publication Date
January 1, 1982
Volume
21
Issue
1
Start / End Page
410 / 413
Related Subject Headings
- Inorganic & Nuclear Chemistry
- 0399 Other Chemical Sciences
- 0306 Physical Chemistry (incl. Structural)
- 0302 Inorganic Chemistry
Citation
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Bennett, D. W., & Spicer, L. D. (1982). The Reaction between Sulfur Dioxide and Hexamethyldisilazane. 2. Oxygen Atom Transfer from Sulfur Dioxide. Inorganic Chemistry, 21(1), 410–413. https://doi.org/10.1021/ic00131a074
Bennett, D. W., and L. D. Spicer. “The Reaction between Sulfur Dioxide and Hexamethyldisilazane. 2. Oxygen Atom Transfer from Sulfur Dioxide.” Inorganic Chemistry 21, no. 1 (January 1, 1982): 410–13. https://doi.org/10.1021/ic00131a074.
Bennett DW, Spicer LD. The Reaction between Sulfur Dioxide and Hexamethyldisilazane. 2. Oxygen Atom Transfer from Sulfur Dioxide. Inorganic Chemistry. 1982 Jan 1;21(1):410–3.
Bennett, D. W., and L. D. Spicer. “The Reaction between Sulfur Dioxide and Hexamethyldisilazane. 2. Oxygen Atom Transfer from Sulfur Dioxide.” Inorganic Chemistry, vol. 21, no. 1, Jan. 1982, pp. 410–13. Scopus, doi:10.1021/ic00131a074.
Bennett DW, Spicer LD. The Reaction between Sulfur Dioxide and Hexamethyldisilazane. 2. Oxygen Atom Transfer from Sulfur Dioxide. Inorganic Chemistry. 1982 Jan 1;21(1):410–413.
Published In
Inorganic Chemistry
DOI
EISSN
1520-510X
ISSN
0020-1669
Publication Date
January 1, 1982
Volume
21
Issue
1
Start / End Page
410 / 413
Related Subject Headings
- Inorganic & Nuclear Chemistry
- 0399 Other Chemical Sciences
- 0306 Physical Chemistry (incl. Structural)
- 0302 Inorganic Chemistry