Scholars@Duke
Journal cover image

The Reaction between Sulfur Dioxide and Hexamethyldisilazane. 2. Oxygen Atom Transfer from Sulfur Dioxide

Publication ,  Journal Article
Bennett, DW; Spicer, LD
Published in: Inorganic Chemistry
January 1, 1982
Published version (DOI)

The new reaction between sulfur dioxide and hexamethyldisilazane, which forms ((CH3)3Si)2O, (CH3)3SiNSO, and NH4(CH3)3SiOSO2, is characterized. In this reaction oxygen is transferred to silicon and sulfur from sulfur dioxide, but Si-N bonding is still partially retained. The solid product, ammonium trimethylsilyl sulfite, sublimes readily at ambient temperature but exhibits ionic properties. The variety of products and the overall reaction stoichiometry impose severe restrictions on possible reaction mechanisms. These constraints are discussed, and a consistent reaction scheme is proposed for this facile but unusual reaction. © 1982, American Chemical Society. All rights reserved.

Duke Scholars

Leonard D. Spicer
Author Leonard D. Spicer Radiology

Published In

Inorganic Chemistry

DOI

10.1021/ic00131a074

EISSN

1520-510X

ISSN

0020-1669

Publication Date

January 1, 1982

Volume

21

Issue

1

Start / End Page

410 / 413

Related Subject Headings

  • Inorganic & Nuclear Chemistry
  • 3403 Macromolecular and materials chemistry
  • 3402 Inorganic chemistry
  • 0399 Other Chemical Sciences
  • 0306 Physical Chemistry (incl. Structural)
  • 0302 Inorganic Chemistry
 

Citation

APA
Chicago
ICMJE
MLA
NLM
Bennett, D. W., & Spicer, L. D. (1982). The Reaction between Sulfur Dioxide and Hexamethyldisilazane. 2. Oxygen Atom Transfer from Sulfur Dioxide. Inorganic Chemistry, 21(1), 410–413. https://doi.org/10.1021/ic00131a074
Bennett, D. W., and L. D. Spicer. “The Reaction between Sulfur Dioxide and Hexamethyldisilazane. 2. Oxygen Atom Transfer from Sulfur Dioxide.” Inorganic Chemistry 21, no. 1 (January 1, 1982): 410–13. https://doi.org/10.1021/ic00131a074.
Bennett DW, Spicer LD. The Reaction between Sulfur Dioxide and Hexamethyldisilazane. 2. Oxygen Atom Transfer from Sulfur Dioxide. Inorganic Chemistry. 1982 Jan 1;21(1):410–3.
Bennett, D. W., and L. D. Spicer. “The Reaction between Sulfur Dioxide and Hexamethyldisilazane. 2. Oxygen Atom Transfer from Sulfur Dioxide.” Inorganic Chemistry, vol. 21, no. 1, Jan. 1982, pp. 410–13. Scopus, doi:10.1021/ic00131a074.
Bennett DW, Spicer LD. The Reaction between Sulfur Dioxide and Hexamethyldisilazane. 2. Oxygen Atom Transfer from Sulfur Dioxide. Inorganic Chemistry. 1982 Jan 1;21(1):410–413.
Journal cover image

Published In

Inorganic Chemistry

DOI

10.1021/ic00131a074

EISSN

1520-510X

ISSN

0020-1669

Publication Date

January 1, 1982

Volume

21

Issue

1

Start / End Page

410 / 413

Related Subject Headings

  • Inorganic & Nuclear Chemistry
  • 3403 Macromolecular and materials chemistry
  • 3402 Inorganic chemistry
  • 0399 Other Chemical Sciences
  • 0306 Physical Chemistry (incl. Structural)
  • 0302 Inorganic Chemistry