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Irradiation of benzene with 14CH+ and 14CH3+ ions

Publication ,  Journal Article
Erwin, WR; Gordon, BE; Spicer, LD; Lemmon, RM
Published in: Journal of Physical Chemistry
1978

Solid benzene at -196 °C was irradiated with 14CH+ and 14CH3+ ions at 10-eV kinetic energy. Yields were determined for the labeled hydrocarbon products: benzene, toluene, cycloheptatriene, diphenylmethane, biphenyl, and phenylcycloheptatriene. The radioactivity distributions between the ring and the methyl group of the toluene product were also determined. These results have been compared to those previously obtained with 14C+ and 14CH2+ ions. The comparisons have provided both insight into the reaction mechanisms and a tentative estimate of the distribution of the species (14CHx) that react with the benzene. © 1978 American Chemical Society.

Duke Scholars

Published In

Journal of Physical Chemistry

ISSN

0022-3654

Publication Date

1978

Volume

82

Issue

6

Start / End Page

654 / 656
 

Citation

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MLA
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Erwin, W. R., Gordon, B. E., Spicer, L. D., & Lemmon, R. M. (1978). Irradiation of benzene with 14CH+ and 14CH3+ ions. Journal of Physical Chemistry, 82(6), 654–656.
Erwin, W. R., B. E. Gordon, L. D. Spicer, and R. M. Lemmon. “Irradiation of benzene with 14CH+ and 14CH3+ ions.” Journal of Physical Chemistry 82, no. 6 (1978): 654–56.
Erwin WR, Gordon BE, Spicer LD, Lemmon RM. Irradiation of benzene with 14CH+ and 14CH3+ ions. Journal of Physical Chemistry. 1978;82(6):654–6.
Erwin, W. R., et al. “Irradiation of benzene with 14CH+ and 14CH3+ ions.” Journal of Physical Chemistry, vol. 82, no. 6, 1978, pp. 654–56.
Erwin WR, Gordon BE, Spicer LD, Lemmon RM. Irradiation of benzene with 14CH+ and 14CH3+ ions. Journal of Physical Chemistry. 1978;82(6):654–656.

Published In

Journal of Physical Chemistry

ISSN

0022-3654

Publication Date

1978

Volume

82

Issue

6

Start / End Page

654 / 656