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Potentiometric determination of solvation numbers and hydration constants for cations

Publication ,  Journal Article
Van Uitert, CE; Spicer, LD; Van Uitert, LGG
Published in: Journal of Physical Chemistry
January 1, 1977

A technique is developed for determining solvation numbers and hydration constants for metal ions. Stability constants are obtained that are essentially independent of the solution composition for a wide range of solvents. It is shown that two ROH molecules can take part in hydronium(-like) complex formation. Solvation numbers are obtained for H+, OH-, and organic acid anions as well as for divalent metal ions and their monochelates.

Duke Scholars

Published In

Journal of Physical Chemistry

DOI

ISSN

0022-3654

Publication Date

January 1, 1977

Volume

81

Issue

1

Start / End Page

40 / 47
 

Citation

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Van Uitert, C. E., Spicer, L. D., & Van Uitert, L. G. G. (1977). Potentiometric determination of solvation numbers and hydration constants for cations. Journal of Physical Chemistry, 81(1), 40–47. https://doi.org/10.1021/j100516a010
Van Uitert, C. E., L. D. Spicer, and L. G. G. Van Uitert. “Potentiometric determination of solvation numbers and hydration constants for cations.” Journal of Physical Chemistry 81, no. 1 (January 1, 1977): 40–47. https://doi.org/10.1021/j100516a010.
Van Uitert CE, Spicer LD, Van Uitert LGG. Potentiometric determination of solvation numbers and hydration constants for cations. Journal of Physical Chemistry. 1977 Jan 1;81(1):40–7.
Van Uitert, C. E., et al. “Potentiometric determination of solvation numbers and hydration constants for cations.” Journal of Physical Chemistry, vol. 81, no. 1, Jan. 1977, pp. 40–47. Scopus, doi:10.1021/j100516a010.
Van Uitert CE, Spicer LD, Van Uitert LGG. Potentiometric determination of solvation numbers and hydration constants for cations. Journal of Physical Chemistry. 1977 Jan 1;81(1):40–47.

Published In

Journal of Physical Chemistry

DOI

ISSN

0022-3654

Publication Date

January 1, 1977

Volume

81

Issue

1

Start / End Page

40 / 47