Deuterium Isotope Effect in Halogen Atom Reactions with Methane and Perdeuteriomethane at Energies above Thermal Thresholds
Publication
, Journal Article
Spicer, LD
Published in: Journal of the American Chemical Society
January 1, 1973
The origin of the isotope effect in the reaction of recoil chlorine atoms with methane and perdeuteriomethane was determined by diluting the systems with inert moderator to establish a unique steady-state collision distribution. The ratio of product yields from the hydrogenated system to those from the deuterated system as a function of moderator suggests that the isotope effect is primarily reactive in nature. The average probability of forming CH3Cl upon collision compared with CD3Cl is about 1.8 and that of forming CH2Cl compared with CD2Cl is about 1.6 in their respective systems. © 1973, American Chemical Society. All rights reserved.
Duke Scholars
Published In
Journal of the American Chemical Society
DOI
EISSN
1520-5126
ISSN
0002-7863
Publication Date
January 1, 1973
Volume
95
Issue
1
Start / End Page
51 / 53
Related Subject Headings
- General Chemistry
- 03 Chemical Sciences
Citation
APA
Chicago
ICMJE
MLA
NLM
Spicer, L. D. (1973). Deuterium Isotope Effect in Halogen Atom Reactions with Methane and Perdeuteriomethane at Energies above Thermal Thresholds. Journal of the American Chemical Society, 95(1), 51–53. https://doi.org/10.1021/ja00782a009
Spicer, L. D. “Deuterium Isotope Effect in Halogen Atom Reactions with Methane and Perdeuteriomethane at Energies above Thermal Thresholds.” Journal of the American Chemical Society 95, no. 1 (January 1, 1973): 51–53. https://doi.org/10.1021/ja00782a009.
Spicer LD. Deuterium Isotope Effect in Halogen Atom Reactions with Methane and Perdeuteriomethane at Energies above Thermal Thresholds. Journal of the American Chemical Society. 1973 Jan 1;95(1):51–3.
Spicer, L. D. “Deuterium Isotope Effect in Halogen Atom Reactions with Methane and Perdeuteriomethane at Energies above Thermal Thresholds.” Journal of the American Chemical Society, vol. 95, no. 1, Jan. 1973, pp. 51–53. Scopus, doi:10.1021/ja00782a009.
Spicer LD. Deuterium Isotope Effect in Halogen Atom Reactions with Methane and Perdeuteriomethane at Energies above Thermal Thresholds. Journal of the American Chemical Society. 1973 Jan 1;95(1):51–53.
Published In
Journal of the American Chemical Society
DOI
EISSN
1520-5126
ISSN
0002-7863
Publication Date
January 1, 1973
Volume
95
Issue
1
Start / End Page
51 / 53
Related Subject Headings
- General Chemistry
- 03 Chemical Sciences