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Ultrafast intermolecular zero quantum spectroscopy.

Publication ,  Journal Article
Galiana, G; Branca, RT; Warren, WS
Published in: Journal of the American Chemical Society
December 2005

Clinical magnetic resonance spectroscopy is typically limited by magnetic inhomogeneities which destroy spectral resolution, but intermolecular zero quantum coherences (iZQCs) are insensitive to such inhomogeneities. iZQC resolution in vivo, however, has been hampered by physiological fluctuations over the time scale of the two-dimensional acquisition. A faster iZQC sequence will allow us to average away these fluctuations, and thus we present a new approach to ultrafast two-dimensional spectroscopy. This communication reports iZQC experiments acquiring up to 31 t1-points per scan, as well as extensions to a broad range of other 2D sequences.

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Published In

Journal of the American Chemical Society

DOI

EISSN

1520-5126

ISSN

0002-7863

Publication Date

December 2005

Volume

127

Issue

50

Start / End Page

17574 / 17575

Related Subject Headings

  • Quantum Theory
  • Oligochaeta
  • Nuclear Magnetic Resonance, Biomolecular
  • General Chemistry
  • Animals
  • 40 Engineering
  • 34 Chemical sciences
  • 03 Chemical Sciences
 

Citation

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Galiana, G., Branca, R. T., & Warren, W. S. (2005). Ultrafast intermolecular zero quantum spectroscopy. Journal of the American Chemical Society, 127(50), 17574–17575. https://doi.org/10.1021/ja054463m
Galiana, Gigi, Rosa T. Branca, and Warren S. Warren. “Ultrafast intermolecular zero quantum spectroscopy.Journal of the American Chemical Society 127, no. 50 (December 2005): 17574–75. https://doi.org/10.1021/ja054463m.
Galiana G, Branca RT, Warren WS. Ultrafast intermolecular zero quantum spectroscopy. Journal of the American Chemical Society. 2005 Dec;127(50):17574–5.
Galiana, Gigi, et al. “Ultrafast intermolecular zero quantum spectroscopy.Journal of the American Chemical Society, vol. 127, no. 50, Dec. 2005, pp. 17574–75. Epmc, doi:10.1021/ja054463m.
Galiana G, Branca RT, Warren WS. Ultrafast intermolecular zero quantum spectroscopy. Journal of the American Chemical Society. 2005 Dec;127(50):17574–17575.
Journal cover image

Published In

Journal of the American Chemical Society

DOI

EISSN

1520-5126

ISSN

0002-7863

Publication Date

December 2005

Volume

127

Issue

50

Start / End Page

17574 / 17575

Related Subject Headings

  • Quantum Theory
  • Oligochaeta
  • Nuclear Magnetic Resonance, Biomolecular
  • General Chemistry
  • Animals
  • 40 Engineering
  • 34 Chemical sciences
  • 03 Chemical Sciences