Mechanistic analysis of gold(I)-catalyzed intramolecular allene hydroalkoxylation reveals an off-cycle bis(gold) vinyl species and reversible C-O bond formation.
Publication
, Journal Article
Brown, TJ; Weber, D; Gagné, MR; Widenhoefer, RA
Published in: Journal of the American Chemical Society
June 2012
Mechanistic investigation of gold(I)-catalyzed intramolecular allene hydroalkoxylation established a mechanism involving rapid and reversible C-O bond formation followed by turnover-limiting protodeauration from a mono(gold) vinyl complex. This on-cycle pathway competes with catalyst aggregation and formation of an off-cycle bis(gold) vinyl complex.
Duke Scholars
Altmetric Attention Stats
Dimensions Citation Stats
Published In
Journal of the American Chemical Society
DOI
EISSN
1520-5126
ISSN
0002-7863
Publication Date
June 2012
Volume
134
Issue
22
Start / End Page
9134 / 9137
Related Subject Headings
- Sorbic Acid
- Molecular Structure
- Models, Molecular
- Gold
- General Chemistry
- Furans
- Catalysis
- 40 Engineering
- 34 Chemical sciences
- 03 Chemical Sciences
Citation
APA
Chicago
ICMJE
MLA
NLM
Brown, T. J., Weber, D., Gagné, M. R., & Widenhoefer, R. A. (2012). Mechanistic analysis of gold(I)-catalyzed intramolecular allene hydroalkoxylation reveals an off-cycle bis(gold) vinyl species and reversible C-O bond formation. Journal of the American Chemical Society, 134(22), 9134–9137. https://doi.org/10.1021/ja303844h
Brown, Timothy J., Dieter Weber, Michel R. Gagné, and Ross A. Widenhoefer. “Mechanistic analysis of gold(I)-catalyzed intramolecular allene hydroalkoxylation reveals an off-cycle bis(gold) vinyl species and reversible C-O bond formation.” Journal of the American Chemical Society 134, no. 22 (June 2012): 9134–37. https://doi.org/10.1021/ja303844h.
Brown TJ, Weber D, Gagné MR, Widenhoefer RA. Mechanistic analysis of gold(I)-catalyzed intramolecular allene hydroalkoxylation reveals an off-cycle bis(gold) vinyl species and reversible C-O bond formation. Journal of the American Chemical Society. 2012 Jun;134(22):9134–7.
Brown, Timothy J., et al. “Mechanistic analysis of gold(I)-catalyzed intramolecular allene hydroalkoxylation reveals an off-cycle bis(gold) vinyl species and reversible C-O bond formation.” Journal of the American Chemical Society, vol. 134, no. 22, June 2012, pp. 9134–37. Epmc, doi:10.1021/ja303844h.
Brown TJ, Weber D, Gagné MR, Widenhoefer RA. Mechanistic analysis of gold(I)-catalyzed intramolecular allene hydroalkoxylation reveals an off-cycle bis(gold) vinyl species and reversible C-O bond formation. Journal of the American Chemical Society. 2012 Jun;134(22):9134–9137.
Published In
Journal of the American Chemical Society
DOI
EISSN
1520-5126
ISSN
0002-7863
Publication Date
June 2012
Volume
134
Issue
22
Start / End Page
9134 / 9137
Related Subject Headings
- Sorbic Acid
- Molecular Structure
- Models, Molecular
- Gold
- General Chemistry
- Furans
- Catalysis
- 40 Engineering
- 34 Chemical sciences
- 03 Chemical Sciences