Scholars@Duke publication: Reaction of CO and tert-butyl isocyanide with the cluster [(C 5Me5)3Co3(μ2-H) 3(μ3-H)] facile hydrogen transfer to isocyanide forms [(C5Me5)3Co3 (μ-H) (μ3-η2-HC=NCMe3)]

Reaction of CO and tert-butyl isocyanide with the cluster [(C 5Me5)3Co3(μ2-H) 3(μ3-H)] facile hydrogen transfer to isocyanide forms [(C5Me5)3Co3 (μ-H) (μ3-η2-HC=NCMe3)]

Publication , Journal Article

Casey, CP; Widenhoefer, RA; Hallenbeck, SL; Gavney, JA

Published in: Journal of the Chemical Society Chemical Communications

December 1, 1993

Published version (DOI)

The reaction of [(C5Me5)3Co 3(μ-2-H)3(μ3-H)] 1 with 2 equiv. of CO forms the biscarbonyl dihydride cluster [(C5Me5) 3Co3(μ3-CO) (μ2-CO)(μ-H) 2] 2; tert-butyl isocyanide inserts into a Co-H bond of 1 to form the formimidoyl monohydride cluster [(C5Me5) 3Co3(μ-H)(μ3-η²-HC= NCMe3)] 5, via the intermediate [(C5Me5) 3Co3(μ3-CNCMe3) (μ2-CNCMe3)(μ-H)2] 6.

Duke Scholars

Author Ross A. Widenhoefer Chemistry

Published In

Journal of the Chemical Society Chemical Communications

DOI

10.1039/C39930001692

ISSN

0022-4936

Publication Date

December 1, 1993

Issue

22

Start / End Page

1692 / 1694

Citation

APA

Chicago

ICMJE

MLA

NLM

Casey, C. P., Widenhoefer, R. A., Hallenbeck, S. L., & Gavney, J. A. (1993). Reaction of CO and tert-butyl isocyanide with the cluster [(C 5Me5)3Co3(μ2-H) 3(μ3-H)] facile hydrogen transfer to isocyanide forms [(C5Me5)3Co3 (μ-H) (μ3-η2-HC=NCMe3)]. Journal of the Chemical Society Chemical Communications, (22), 1692–1694. https://doi.org/10.1039/C39930001692

Casey, C. P., R. A. Widenhoefer, S. L. Hallenbeck, and J. A. Gavney. “Reaction of CO and tert-butyl isocyanide with the cluster [(C 5Me5)3Co3(μ2-H) 3(μ3-H)] facile hydrogen transfer to isocyanide forms [(C5Me5)3Co3 (μ-H) (μ3-η2-HC=NCMe3)].” Journal of the Chemical Society Chemical Communications, no. 22 (December 1, 1993): 1692–94. https://doi.org/10.1039/C39930001692.

Casey CP, Widenhoefer RA, Hallenbeck SL, Gavney JA. Reaction of CO and tert-butyl isocyanide with the cluster [(C 5Me5)3Co3(μ2-H) 3(μ3-H)] facile hydrogen transfer to isocyanide forms [(C5Me5)3Co3 (μ-H) (μ3-η2-HC=NCMe3)]. Journal of the Chemical Society Chemical Communications. 1993 Dec 1;(22):1692–4.

Casey, C. P., et al. “Reaction of CO and tert-butyl isocyanide with the cluster [(C 5Me5)3Co3(μ2-H) 3(μ3-H)] facile hydrogen transfer to isocyanide forms [(C5Me5)3Co3 (μ-H) (μ3-η2-HC=NCMe3)].” Journal of the Chemical Society Chemical Communications, no. 22, Dec. 1993, pp. 1692–94. Scopus, doi:10.1039/C39930001692.

Casey CP, Widenhoefer RA, Hallenbeck SL, Gavney JA. Reaction of CO and tert-butyl isocyanide with the cluster [(C 5Me5)3Co3(μ2-H) 3(μ3-H)] facile hydrogen transfer to isocyanide forms [(C5Me5)3Co3 (μ-H) (μ3-η2-HC=NCMe3)]. Journal of the Chemical Society Chemical Communications. 1993 Dec 1;(22):1692–1694.

Published In

Journal of the Chemical Society Chemical Communications

DOI

10.1039/C39930001692

ISSN

0022-4936

Publication Date

December 1, 1993

Issue

22

Start / End Page

1692 / 1694