Journal ArticleAdvanced Materials Interfaces · September 3, 2024
The interplay of lattice, electronic, and spin degrees of freedom at epitaxial complex oxide interfaces provides a route to tune their magnetic ground states. Unraveling the competing contributions is critical for tuning their functional properties. The re ...
Full textCite
Journal ArticlePhysical Review Materials · September 1, 2024
In ferromagnetic oxide epitaxial multilayers, magnetic properties and interlayer coupling are determined by a variety of factors. Beyond the contribution of interlayer exchange coupling, strain and interfacial effects, such as structural reconstructions or ...
Full textCite
Journal ArticleAdvanced Physics Research · March 2024
AbstractThe structural and transport properties of vacancy‐ordered monoclinic superconducting titanium oxide (TiO) thin films grown by molecular beam epitaxy are investigated. The evolution of the crystal structure during g ...
Full textOpen AccessCite
Journal ArticleNature Physics · January 1, 2024
Complex oxides have competing phases with different spin, electronic and orbital order. Now it has been shown that growing thin films on different facets of a low-symmetry substrate can be used to control the phase of the ground state. ...
Full textCite
Journal ArticleNew Physics: Sae Mulli · December 1, 2023
The perovskite BaBiO3 crystallizes in a cubic structure and undergoes structural transitions toward lower symmetry phases upon cooling. The two low-temperature monoclinic phases are insulating, and the origin of this unexpected non-metallic character has b ...
Full textCite
Journal ArticleNano letters · August 2023
The nature of superconductivity and its interplay with strong spin-orbit coupling at the KTaO3(111) interfaces remain a subject of debate. To address this problem, we grew epitaxial LaMnO3/KTaO3(111) heterostructures. We sh ...
Full textCite
Journal ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany) · July 2023
Nanosized perovskite ferroelectrics are widely employed in several electromechanical, photonics, and thermoelectric applications. Scaling of ferroelectric materials entails a severe reduction in the lattice (phonon) thermal conductivity, particularly at su ...
Full textCite
Journal ArticleAdvanced materials (Deerfield Beach, Fla.) · June 2023
Acting like thermal resistances, ferroelectric domain walls can be manipulated to realize dynamic modulation of thermal conductivity (k), which is essential for developing novel phononic circuits. Despite the interest, little attention has been paid to ach ...
Full textCite
Journal ArticleAdvanced Engineering Materials · May 1, 2023
A facile and novel processable method to synthesize the Ni nanoparticles (Ni NPs) by tailoring their size in the matrix of the silicon oxycarbide (SiOC) ceramic system is reported. This method is based on polymer-derived ceramics (PDCs), instead of the con ...
Full textCite
Journal ArticleScience advances · February 2023
A two-dimensional, anisotropic superconductivity was recently found at the KTaO3(111) interfaces. The nature of the anisotropic superconducting transition remains a subject of debate. To investigate the origins of the observed behavior, we grew ...
Full textCite
Journal ArticleJournal of Electronic Materials · December 1, 2022
The anomalous Hall effect, a hallmark of broken time-reversal symmetry and spin–orbit coupling, is frequently observed in magnetically polarized systems. However, its realization in nominally non-magnetic systems remains elusive. Here, we report on the obs ...
Full textCite
Journal ArticleJournal of Electronic Materials · November 1, 2022
The intersection of two-dimensional superconductivity and topologically nontrivial states hosts a wide range of quantum phenomena, including Majorana fermions. We report on the observation of two-dimensional superconductivity and weak anti-localization at ...
Full textCite
Journal ArticlePhysical Review Materials · June 1, 2022
We investigate the complex relationship between the growth conditions and the structural and transport properties of TixOy thin films grown by molecular beam epitaxy. Transport properties ranging from metallicity to superconductivity and insulating states ...
Full textCite
Journal ArticleAPL Materials · May 1, 2022
The temperature-dependent layer-resolved structure of 3 to 44 unit cell thick SrRuO3 (SRO) films grown on Nb-doped SrTiO3 substrates is investigated using a combination of high-resolution synchrotron x-ray diffraction and high-resolution electron microscop ...
Full textCite
Journal ArticleJournal of Vacuum Science and Technology A: Vacuum, Surfaces and Films · January 1, 2022
The control of chemical exchange across heterointerfaces formed between ultrathin functional transition-metal oxide layers provides an effective route to manipulate the electronic properties of these systems. By determining the layer-resolved structural pr ...
Full textCite
Journal ArticleApplied Physics Letters · May 10, 2021
The strong interfacial coupling at the 3d-5d transition metal-oxide interfaces has generated excitement due to the possibility of engineering a wide range of quantum phenomena and functionalities. Here, we investigate the electronic interfacial coupling an ...
Full textCite
Journal ArticleJournal of Applied Physics · February 7, 2021
We investigate the structural and magnetic properties of La 0.7 Sr 0.3 CrO 3 (LSCO) / La 0.7 Sr 0.3 MnO 3 (LSMO) heterostructures grown on (001)-oriented MgO by molecular beam epitaxy. Due to the large film-substrate lattice mismatch, strain relaxation is ...
Full textCite
Journal ArticlePhysical Review Materials · August 1, 2020
Manipulating spin-orbit coupling (SOC) is a key achievement for spin-orbitronic applications since SOC determines spin-diffusion lengths and spin-to-charge conversion efficiencies. While in most organic semiconductors SOC is inherently very weak due to bei ...
Full textCite
Journal ArticleAdvanced Functional Materials · May 1, 2020
Functional oxides are an untapped resource for futuristic devices and functionalities. These functionalities can range from high temperature superconductivity to multiferroicity and novel catalytic schemes. The most prominent route for transforming these i ...
Full textCite
Journal ArticleAIP Advances · April 1, 2020
The atomic and electronic structures of La0.7Sr0.3MnO3 (LSMO)/La0.7Sr0.3CrO3 (LSCO) multilayer thin films are investigated using aberration corrected scanning transmission electron microscopy (STEM) imaging and spectroscopy. Atomic resolution high angle an ...
Full textCite
Journal ArticleAIP Advances · April 1, 2020
The relationship between the sheet carrier concentration, ns, of LaCrO3(LCO)/SrTiO3(STO) heterostructures and their structural properties has been investigated. Under low oxygen partial pressure, the STO substrate is reduced during growth as evidenced by a ...
Full textCite
Journal ArticlePhysical Review B · February 1, 2020
We investigate the effect of strain and film thickness on the orbital and magnetic properties of LaSrCrO3(LSCO)/LaSrMnO3 (LSMO) heterostructures using bulk magnetometry, soft X-ray magnetic spectroscopy, first-principles density-functional theory, high-res ...
Full textCite
Journal ArticleAIP Advances · January 1, 2020
In the recent past, heterostructures of magnetic oxide thin films have attracted a great deal of research excitement due to very interesting physical properties such as antiferromagnetic interlayer coupling, tunable exchange-bias, interfacial driven magnet ...
Full textCite
Journal ArticleJournal of Vacuum Science and Technology A: Vacuum, Surfaces and Films · January 1, 2020
Wet-etch techniques to realize suspended microscale structures of single-crystalline SrTiO3 and BaTiO3 grown on Si are explored. The authors examine the effects of oxygen vacancies and dislocations on etch rates. Both oxygen vacancies and dislocations enha ...
Full textCite
Journal Articlenpj Quantum Materials · December 1, 2019
At crystalline interfaces where a valence-mismatch exists, electronic, and structural interactions may occur to relieve the polar mismatch, leading to the stabilization of non-bulk-like phases. We show that spontaneous reconstructions at polar La0.7Sr0.3Mn ...
Full textCite
Journal ArticleJournal of Vacuum Science and Technology A: Vacuum, Surfaces and Films · March 1, 2019
The effect of growth conditions and postgrowth treatment on the structural and electronic properties of the polar/nonpolar LaCrO3/SrTiO3 (LCO/STO) interface has been investigated. Under low oxygen partial pressure, oxygen vacancies are formed in the STO su ...
Full textCite
Journal ArticleApplied Physics Letters · November 12, 2018
The interfacial structure of SrZrxTi1-xO3 films grown on semiconducting Ge substrates is investigated by synchrotron X-ray diffraction and first-principles density functional theory. By systematically tuning the Zr content x, the effects of bonding at the ...
Full textCite
Journal ArticleApplied Physics Letters · May 7, 2018
We present electrical and structural characterization of epitaxial LaTiO3/SrTiO3 heterostructures integrated directly on Si(100). By reducing the thicknesses of the heterostructures, an enhancement in carrier-carrier scattering is observed in the Fermi liq ...
Full textCite
Journal ArticleNano letters · January 2018
A single atomic layer of ZrO2 exhibits ferroelectric switching behavior when grown with an atomically abrupt interface on silicon. Hysteresis in capacitance-voltage measurements of a ZrO2 gate stack demonstrate that a reversible polar ...
Full textCite
Journal ArticlePhysical Review B · July 31, 2017
Electronic, lattice, and spin interactions at the interfaces between crystalline complex transition-metal oxides can give rise to a wide range of functional electronic and magnetic phenomena not found in bulk. At heterointerfaces, these interactions may be ...
Full textCite
Journal ArticlePhysical Review Materials · July 27, 2017
The combination of charge and spin degrees of freedom with electronic correlations in condensed matter systems leads to a rich array of phenomena, such as magnetism, superconductivity, and novel conduction mechanisms. While such phenomena are observed in b ...
Full textCite
Journal ArticleJournal of Materials Research · January 27, 2017
Complex oxides and semiconductors exhibit distinct yet complementary properties owing to their respective ionic and covalent natures. By electrically coupling complex oxides to traditional semiconductors within epitaxial heterostructures, enhanced or novel ...
Full textCite
Journal ArticlePhysical Review B · May 16, 2016
We determine the surface reconstruction of SrTiO3 used to achieve superconducting FeSe films in experiments, which is different from the 1×1TiO2-terminated SrTiO3 assumed by most previous theoretical studies. In particular, we identify the existence of a d ...
Full textCite
Journal ArticlePhysical review letters · March 2016
The strong interaction at an interface between a substrate and thin film leads to epitaxy and provides a means of inducing structural changes in the epitaxial film. These induced material phases often exhibit technologically relevant electronic, magnetic, ...
Full textCite
ConferenceMRS Advances · January 1, 2016
Complex oxides and semiconductors exhibit distinct yet complementary properties owing to their respective ionic and covalent natures. By electrically coupling oxides to semiconductors within epitaxial heterostructures, enhanced or novel functionalities bey ...
Full textCite
Journal ArticleApplied Physics Letters · May 18, 2015
Two dimensional electron gases (2DEGs) formed at the interfaces of oxide heterostructures draw considerable interest owing to their unique physics and potential applications. Growing such heterostructures on conventional semiconductors has the potential to ...
Full textCite
Journal ArticlePhysical review letters · January 2015
We experimentally demonstrate a novel approach to substantially modify orbital occupations and symmetries in electronically correlated oxides. In contrast to methods using strain or confinement, this orbital tuning is achieved by exploiting charge transfer ...
Full textCite
Journal ArticlePhysical Review Applied · November 6, 2014
The electronic and structural properties of thin LaNiO3 films grown by using molecular beam epitaxy are studied as a function of the net ionic charge of the surface terminating layer. We demonstrate that electronic transport in nickelate heterostructures c ...
Full textCite
Journal ArticleAPL Materials · November 1, 2014
We present the growth and characterization of layered heterostructures comprised of LaTiO3 and SrTiO3 epitaxially grown on Si (001). Magnetotransport measurements show that the sheet carrier densities of the heterostructures scale with the number of LaTiO3 ...
Full textCite
Journal ArticleApplied Physics Letters · October 2, 2014
We present electrical transport measurements of heterostructures comprised of BaTiO3 and Ba1-xSrxTiO3 epitaxially grown on Ge. Sr alloying imparts compressive strain to the BaTiO3, which enables the thermal expansion mismatch between BaTiO3 and Ge to be ov ...
Full textCite
Journal ArticleNano letters · March 2014
The integration of complex oxides on silicon presents opportunities to extend and enhance silicon technology with novel electronic, magnetic, and photonic properties. Among these materials, barium titanate (BaTiO3) is a particularly strong ferroelectric pe ...
Full textCite
Journal ArticleAdvanced materials (Deerfield Beach, Fla.) · March 2014
Metallic electronic transport in nickelate heterostructures can be induced and confined to two dimensions (2D) by controlling the structural parameters of the nickel-oxygen planes. ...
Full textCite
ConferenceConference on Lasers and Electro-Optics Europe - Technical Digest · January 1, 2014
A Si-integrated modulator based on epitaxial ferroelectric BaTiO3 thin films is demonstrated with gigahertz modulation bandwidth and an effective Pockels coefficient of 213 ± 49 pm/V. ...
Cite
Journal ArticlePhysical review letters · May 2013
We describe a general materials design approach that produces large orbital energy splittings (orbital polarization) in nickelate heterostructures, creating a two-dimensional single-band electronic surface at the Fermi energy. The resulting electronic stru ...
Full textCite
Journal ArticleAPL Materials · January 1, 2013
The complex phase diagrams of strongly correlated oxides arise from the coupling between physical and electronic structure. This can lead to a renormalization of the phase boundaries when considering thin films rather than bulk crystals due to reduced dime ...
Full textCite
Journal ArticleAPL Materials · January 1, 2013
We demonstrate a route to manipulate the polarization and internal electric field of a complex oxide heterostructure using a layering sequence based on the LaAlO3-SrTiO3 interface. By combining sensitive atomic-level mapping of the structure using direct x ...
Full textCite
Journal ArticleJournal of Magnetism and Magnetic Materials · January 1, 2013
The magnetic structure of Fe-doped CoFe2O4 (Co 1-xFe2+xO4) grown on MgO (0 0 1) and SrTiO 3 (0 0 1) substrates is studied with superconducting quantum interference device magnetometry and soft x-ray magnetic spectroscopies. X-ray and electron diffraction s ...
Full textCite
Journal ArticlePhysical Review B - Condensed Matter and Materials Physics · November 5, 2012
The effect of film thickness on the magnetic properties of ultrathin Fe-doped cobalt ferrite (Co 1-xFe 2+xO 4) grown on MgO (001) substrates is investigated by superconducting quantum interference device magnetometry and x-ray magnetic linear dichroism, wh ...
Full textCite
Journal ArticleApplied Physics Letters · September 3, 2012
Thin films of epitaxial SrTiO 3 grown on silicon exhibit compressive in-plane strain that may stabilize ferroelectricity in this normally non-ferroelectric material. We investigate this possibility by using an ultra-high vacuum atomic force microscope to m ...
Full textCite
Journal ArticleApplied Physics Letters · July 9, 2012
The distribution of cations in Fe-doped cobalt ferrite (Co 1-xFe 2xO 4) is investigated as a function of epitaxial strain through x-ray absorption measurements of samples grown on SrTiO 3, MgO, and CoCr 2O 4-buffered MgAl 2O 4 (001). In agreement with rece ...
Full textCite
Journal ArticlePhysical Review B - Condensed Matter and Materials Physics · August 15, 2011
The magnetic properties of iron-doped cobalt ferrite (Co 1-xFe2+xO4) (001) thin films grown epitaxially on MgO (001) substrates are investigated by superconducting quantum interference device magnetometry and soft x-ray magnetic linear and circular dichroi ...
Full textCite
Journal ArticleApplied Physics Letters · June 13, 2011
We have used a direct x-ray phasing method, coherent Bragg rod analysis, to obtain sub-angstrom resolution electron density maps of the InAs/GaAs dot system. The dots were grown by the droplet heteroepitaxy (DHE) technique and their structural and composit ...
Full textCite
Journal ArticleApplied Physics Letters · January 10, 2011
We report on the use of a direct x-ray phase retrieval method, coherent Bragg rod analysis, to characterize self-assembled InAs quantum dots (QDs) grown epitaxially on GaAs substrates. Electron density maps obtained close to the x-ray absorption edges of t ...
Full textCite
Journal ArticleSensors (Basel, Switzerland) · January 2011
In recent years, epitaxial growth of self-assembled quantum dots has offered a way to incorporate new properties into existing solid state devices. Although the droplet heteroepitaxy method is relatively complex, it is quite relaxed with respect to the mat ...
Full textCite
Journal ArticleApplied Physics Letters · December 20, 2010
For thin film devices based on coupling ferroelectric polarization to charge carriers in semiconductors, the role of the interface is critical. To elucidate this role, we use synchrotron x-ray diffraction to determine the interface structure of epitaxial S ...
Full textCite
Journal ArticleNature nanotechnology · December 2009
Quantum dots (QDs) have applications in optoelectronic devices, quantum information processing and energy harvesting. Although the droplet epitaxy fabrication method allows for a wide range of material combinations to be used, little is known about the gro ...
Full textCite
ConferenceAIP Conference Proceedings · April 23, 2009
The availability of high-brilliance hard x-ray synchrotron radiation and the advent of novel photon counting area detectors have brought surface x-ray diffraction (SXRD) into a new era. It is now possible to record large numbers of structure factors with m ...
Full textCite
Journal ArticleActa Materialia · October 1, 2008
Solidification of single-crystal nickel-base superalloys introduces large-scale segregation of constituent elements and defects such as dislocations and mosaicity. By exploiting the energy tunability and interference capabilities of high-brilliance X-ray r ...
Full textCite
Journal ArticleApplied Physics Letters · September 15, 2008
The resonant response of the complex x-ray scattering factor has been used in conjunction with the coherent Bragg rod analysis phase-retrieval algorithm to determine the composition and strain profiles of ultrathin layers of GaAs grown on InGaAs buffers. T ...
Full textCite
Journal ArticleApplied Physics Letters · April 24, 2008
We have used surface x-ray diffraction and a direct method of phase reconstruction to obtain subangström resolution maps of an ion-beam milled In0.27 Ga0.73 AsGaAs (001) thin film exhibiting three-dimensional (3D) epitaxial nanostructures. The 3D electron ...
Full textCite
Journal ArticlePhysical Review B - Condensed Matter and Materials Physics · February 1, 2008
Surface x-ray diffraction was used to determine the atomic structures of La1-x Srx MnO3 thin films, grown monolayer by monolayer on SrTiO3 by pulsed laser deposition. Structures for one-, two-, three-, four-, six-, and nine-monolayer-thick films were solve ...
Full textCite
ConferenceJournal of Engineering Materials and Technology · January 1, 2008
A novel X-ray synchrotron radiation approach is described for real-time imaging of the initiation and growth of fatigue cracks during ultrasonic fatigue (f=20 kHz). We report here on new insights on single crystal nickel-base superalloys gained with this a ...
Full textCite
Journal ArticlePhysical review letters · October 2007
The complete atomic structure of a five-monolayer film of LaAlO3 on SrTiO3 has been determined for the first time by surface x-ray diffraction in conjunction with the coherent Bragg rod analysis phase-retrieval method and further structural refinement. Cat ...
Full textCite
Journal ArticleJournal of Physics D: Applied Physics · May 7, 2007
Au/Co/Au trilayers are interesting for a range of applications which exploit their unusual optical and electronic transport behaviour in a magnetic field. Here we present a comprehensive structural and morphological study of a series of trilayers with 0-7 ...
Full textCite
Journal ArticleApplied Physics Letters · January 15, 2007
The authors use Fresnel diffraction from knife-edges to demonstrate the spatial coherence of a tabletop ultrafast x-ray source produced by laser-plasma interaction. Spatial coherence is achieved in the far field by producing micrometer-scale x-ray spot dim ...
Full textCite
Journal ArticlePhysical Review B - Condensed Matter and Materials Physics · January 1, 2007
We demonstrate magnetic field control of surface plasmon excitations in noble-metal/ferromagnetic/noble metal trilayers, analogous to the effects previously observed in semiconductor structures. We show that the coupling of an external magnetic field to th ...
Full textCite