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Brian R. Stoner

Research Professor in the Department of Electrical and Computer Engineering
Electrical and Computer Engineering

Selected Publications


Designing Pilot Treatment Systems for Evaluation of Passive Nitrogen and Phosphorus Filtration in Stormwater

Conference 2024 Systems and Information Engineering Design Symposium, SIEDS 2024 · January 1, 2024 High concentrations of nitrogen and phosphorous, commonly introduced to stormwater through urban runoff, agricultural processes, and domestic wastewater infrastructure, contribute to algal blooms, which can be harmful and sometimes toxic to humans and aqua ... Full text Cite

Proof-of-Concept Vacuum Microelectronic NOR Gate Fabricated Using Microelectromechanical Systems and Carbon Nanotube Field Emitters.

Journal Article Micromachines · April 2023 This paper demonstrates a fully integrated vacuum microelectronic NOR logic gate fabricated using microfabricated polysilicon panels oriented perpendicular to the device substrate with integrated carbon nanotube (CNT) field emission cathodes. The vacuum mi ... Full text Cite

Predictive values of time-dense SARS-CoV-2 wastewater analysis in university campus buildings.

Journal Article The Science of the total environment · August 2022 Wastewater-based SARS-CoV-2 surveillance on college campuses has the ability to detect individual clinical COVID-19 cases at the building-level. High concordance of wastewater results and clinical cases has been observed when calculated over a time window ... Full text Cite

A hands-free stool sampling system for monitoring intestinal health and disease.

Journal Article Sci Rep · June 27, 2022 Analysis of stool offers simple, non-invasive monitoring for many gastrointestinal (GI) diseases and access to the gut microbiome, however adherence to stool sampling protocols remains a major challenge because of the prevalent dislike of handling one's fe ... Full text Link to item Cite

Rheological characterisation of synthetic and fresh faeces to inform on solids management strategies for non-sewered sanitation systems.

Journal Article Journal of environmental management · December 2021 In order to obviate the economic issues associated with pit latrine emptying and transport such as high water additions and rheologically difficult sludge properties, the implications of prompt solid/liquid separation were investigated. This was achieved t ... Full text Cite

On the compressional rheology of fresh faeces: Evidence for improving community scale sanitation through localised dewatering.

Journal Article Water research · October 2021 Non-sewered sanitation is currently dependant upon pit latrine emptying, the safety of which is compromised by the high costs of faecal sludge transport to centralised treatment facilities. Transport in turn is hindered by the complex rheology of pit latri ... Full text Cite

The Long Neglected Cycloidal Mass Analyzer.

Journal Article Analytical chemistry · August 2021 In 1938, Walker Bleakney and John A. Hipple first described the cycloidal mass analyzer as the only mass analyzer configuration capable of "perfect" ion focusing. Why has their geometry been largely neglected for many years and how might it earn a respecta ... Full text Cite

Physical properties of menstrual hygiene waste as feedstock for onsite disposal technologies

Journal Article Journal of Water Sanitation and Hygiene for Development · May 1, 2021 Onsite incinerators offer a promising solution to the challenges of menstrual waste disposal, particularly in institutional settings. However, thermochemical processes are well known to depend on the nature of the feedstocks and their moisture content (MC) ... Full text Cite

Improving the Performance of a Cycloidal Coded-Aperture Miniature Mass Spectrometer.

Journal Article Journal of the American Society for Mass Spectrometry · February 2021 Cycloidal sector mass analyzers have, in principle, perfect focusing due to perpendicularly oriented uniform electric and magnetic fields, making them ideal candidates for incorporation of spatially coded apertures. We have previously demonstrated a proof- ... Full text Cite

Drying kinetics characteristics of human fecal matter for the development of onsite sanitation technologies

Journal Article Journal of Solid Waste Technology and Management · February 1, 2021 This study aims to define the drying kinetics of two types of human fecal matter, stabilized sludge removed from South African pit latrines and unstabilized fresh fecal material collected from healthy donors in the United States. For the purposes of this s ... Full text Cite

Laboratory Demonstration and Preliminary Techno-Economic Analysis of an Onsite Wastewater Treatment System.

Journal Article Environmental science & technology · December 2020 Providing safe and reliable sanitation services to the billions of people currently lacking them will require a multiplicity of approaches. Improving onsite wastewater treatment to standards enabling water reuse would reduce the need to transport waste and ... Full text Cite

Comparison of thermionic filament and carbon nanotube field emitter-based electron ionization sources in cycloidal coded aperture mass analyzers

Journal Article International Journal of Mass Spectrometry · November 1, 2020 This work compares the coded aperture imaging performance of thermionic filament and carbon nanotube (CNT) field emitter-based electron sources in cycloidal-coded aperture mass spectrometers. The use of spatially coded apertures in mass spectrometry enable ... Full text Cite

Resolving the relative contributions of cistern and pour flushing to toilet water usage: Measurements from urban test sites in India.

Journal Article The Science of the total environment · August 2020 A challenge in water reuse for toilet flushing in India and other Asian countries derives from pour flushing practices. It is a common assumption that the amount of pour flushed water used for personal cleansing is small in comparison to the cistern flush ... Full text Cite

A Gender Lens into Sanitation Technology Innovation

Journal Article Journal of Management in Engineering · July 1, 2020 Innovators in the water and sanitation sector are focused on closing the sanitation gap in developing countries through innovation in technologies that enable waste treatment onsite. To ensure universal access, these technologies need to meet the practices ... Full text Cite

Field testing of a household-scale onsite blackwater treatment system in Coimbatore, India.

Journal Article The Science of the total environment · April 2020 4.2 billion people live without access to safely managed sanitation services. This report describes the field testing of an onsite prototype system designed to treat blackwater from a single flush toilet and reuse of the treated effluent for flushing. The ... Full text Cite

Field testing of a household-scale onsite blackwater treatment system in South Africa.

Journal Article The Science of the total environment · February 2020 Innovations that enable cost-effective and resource-conserving treatment of human waste are required for the 4.2 billion people in the world who currently lack safe and reliable sanitation services. Onsite treatment and reuse of blackwater is one strategy ... Full text Cite

Deactivation of ascaris suum eggs using electroporation and sequential inactivation with chemical disinfection

Journal Article Journal of Water Sanitation and Hygiene for Development · January 1, 2020 Electroporation has been evaluated as a potential backend wastewater treatment for deactivation of Ascaris suum eggs in buffer solution. Initial results indicate that eggshell permeability is affected by the pulse train electric field strength and duration ... Full text Cite

Non-biological methods for phosphorus and nitrogen removal from wastewater: A gap analysis of reinvented-toilet technologies with respect to ISO 30500

Journal Article · February 24, 2019 The aims of the Reinvent the Toilet Challenge (RTTC) include creation of an off-the-grid sanitation system with operating costs of less than US$0.05 per user per day. Because of the small scale at which many reinvented toilets (RT) are intended to operate, ... Full text Cite

Remediation of suspended solids and turbidity by improved settling tank design in a small-scale, free-standing toilet system using recycled blackwater.

Journal Article Water and environment journal : the journal · February 2019 Our research is focused on the development of decentralized waste water treatment technologies enabling onsite water reuse. Accumulation of solids with recycling of treated blackwater increases the energy required for disinfection with an electrochemical p ... Full text Cite

Reduction in energy for electrochemical disinfection of E. coli in urine simulant.

Journal Article Journal of applied electrochemistry · January 2019 AbstractWe report the development of novel modes of operation for electrochemical disinfection of E. coli in human urine simulant with an aim to minimize the energy required for disinfection. The system employs boron-doped diamond electrode ... Full text Cite

Designing Pilot Treatment Systems for Evaluation of Passive Nitrogen and Phosphorus Filtration in Stormwater

Conference 2024 Systems and Information Engineering Design Symposium, SIEDS 2024 · January 1, 2024 High concentrations of nitrogen and phosphorous, commonly introduced to stormwater through urban runoff, agricultural processes, and domestic wastewater infrastructure, contribute to algal blooms, which can be harmful and sometimes toxic to humans and aqua ... Full text Cite

Proof-of-Concept Vacuum Microelectronic NOR Gate Fabricated Using Microelectromechanical Systems and Carbon Nanotube Field Emitters.

Journal Article Micromachines · April 2023 This paper demonstrates a fully integrated vacuum microelectronic NOR logic gate fabricated using microfabricated polysilicon panels oriented perpendicular to the device substrate with integrated carbon nanotube (CNT) field emission cathodes. The vacuum mi ... Full text Cite

Predictive values of time-dense SARS-CoV-2 wastewater analysis in university campus buildings.

Journal Article The Science of the total environment · August 2022 Wastewater-based SARS-CoV-2 surveillance on college campuses has the ability to detect individual clinical COVID-19 cases at the building-level. High concordance of wastewater results and clinical cases has been observed when calculated over a time window ... Full text Cite

A hands-free stool sampling system for monitoring intestinal health and disease.

Journal Article Sci Rep · June 27, 2022 Analysis of stool offers simple, non-invasive monitoring for many gastrointestinal (GI) diseases and access to the gut microbiome, however adherence to stool sampling protocols remains a major challenge because of the prevalent dislike of handling one's fe ... Full text Link to item Cite

Rheological characterisation of synthetic and fresh faeces to inform on solids management strategies for non-sewered sanitation systems.

Journal Article Journal of environmental management · December 2021 In order to obviate the economic issues associated with pit latrine emptying and transport such as high water additions and rheologically difficult sludge properties, the implications of prompt solid/liquid separation were investigated. This was achieved t ... Full text Cite

On the compressional rheology of fresh faeces: Evidence for improving community scale sanitation through localised dewatering.

Journal Article Water research · October 2021 Non-sewered sanitation is currently dependant upon pit latrine emptying, the safety of which is compromised by the high costs of faecal sludge transport to centralised treatment facilities. Transport in turn is hindered by the complex rheology of pit latri ... Full text Cite

The Long Neglected Cycloidal Mass Analyzer.

Journal Article Analytical chemistry · August 2021 In 1938, Walker Bleakney and John A. Hipple first described the cycloidal mass analyzer as the only mass analyzer configuration capable of "perfect" ion focusing. Why has their geometry been largely neglected for many years and how might it earn a respecta ... Full text Cite

Physical properties of menstrual hygiene waste as feedstock for onsite disposal technologies

Journal Article Journal of Water Sanitation and Hygiene for Development · May 1, 2021 Onsite incinerators offer a promising solution to the challenges of menstrual waste disposal, particularly in institutional settings. However, thermochemical processes are well known to depend on the nature of the feedstocks and their moisture content (MC) ... Full text Cite

Improving the Performance of a Cycloidal Coded-Aperture Miniature Mass Spectrometer.

Journal Article Journal of the American Society for Mass Spectrometry · February 2021 Cycloidal sector mass analyzers have, in principle, perfect focusing due to perpendicularly oriented uniform electric and magnetic fields, making them ideal candidates for incorporation of spatially coded apertures. We have previously demonstrated a proof- ... Full text Cite

Drying kinetics characteristics of human fecal matter for the development of onsite sanitation technologies

Journal Article Journal of Solid Waste Technology and Management · February 1, 2021 This study aims to define the drying kinetics of two types of human fecal matter, stabilized sludge removed from South African pit latrines and unstabilized fresh fecal material collected from healthy donors in the United States. For the purposes of this s ... Full text Cite

Laboratory Demonstration and Preliminary Techno-Economic Analysis of an Onsite Wastewater Treatment System.

Journal Article Environmental science & technology · December 2020 Providing safe and reliable sanitation services to the billions of people currently lacking them will require a multiplicity of approaches. Improving onsite wastewater treatment to standards enabling water reuse would reduce the need to transport waste and ... Full text Cite

Comparison of thermionic filament and carbon nanotube field emitter-based electron ionization sources in cycloidal coded aperture mass analyzers

Journal Article International Journal of Mass Spectrometry · November 1, 2020 This work compares the coded aperture imaging performance of thermionic filament and carbon nanotube (CNT) field emitter-based electron sources in cycloidal-coded aperture mass spectrometers. The use of spatially coded apertures in mass spectrometry enable ... Full text Cite

Resolving the relative contributions of cistern and pour flushing to toilet water usage: Measurements from urban test sites in India.

Journal Article The Science of the total environment · August 2020 A challenge in water reuse for toilet flushing in India and other Asian countries derives from pour flushing practices. It is a common assumption that the amount of pour flushed water used for personal cleansing is small in comparison to the cistern flush ... Full text Cite

A Gender Lens into Sanitation Technology Innovation

Journal Article Journal of Management in Engineering · July 1, 2020 Innovators in the water and sanitation sector are focused on closing the sanitation gap in developing countries through innovation in technologies that enable waste treatment onsite. To ensure universal access, these technologies need to meet the practices ... Full text Cite

Field testing of a household-scale onsite blackwater treatment system in Coimbatore, India.

Journal Article The Science of the total environment · April 2020 4.2 billion people live without access to safely managed sanitation services. This report describes the field testing of an onsite prototype system designed to treat blackwater from a single flush toilet and reuse of the treated effluent for flushing. The ... Full text Cite

Field testing of a household-scale onsite blackwater treatment system in South Africa.

Journal Article The Science of the total environment · February 2020 Innovations that enable cost-effective and resource-conserving treatment of human waste are required for the 4.2 billion people in the world who currently lack safe and reliable sanitation services. Onsite treatment and reuse of blackwater is one strategy ... Full text Cite

Deactivation of ascaris suum eggs using electroporation and sequential inactivation with chemical disinfection

Journal Article Journal of Water Sanitation and Hygiene for Development · January 1, 2020 Electroporation has been evaluated as a potential backend wastewater treatment for deactivation of Ascaris suum eggs in buffer solution. Initial results indicate that eggshell permeability is affected by the pulse train electric field strength and duration ... Full text Cite

Non-biological methods for phosphorus and nitrogen removal from wastewater: A gap analysis of reinvented-toilet technologies with respect to ISO 30500

Journal Article · February 24, 2019 The aims of the Reinvent the Toilet Challenge (RTTC) include creation of an off-the-grid sanitation system with operating costs of less than US$0.05 per user per day. Because of the small scale at which many reinvented toilets (RT) are intended to operate, ... Full text Cite

Remediation of suspended solids and turbidity by improved settling tank design in a small-scale, free-standing toilet system using recycled blackwater.

Journal Article Water and environment journal : the journal · February 2019 Our research is focused on the development of decentralized waste water treatment technologies enabling onsite water reuse. Accumulation of solids with recycling of treated blackwater increases the energy required for disinfection with an electrochemical p ... Full text Cite

Reduction in energy for electrochemical disinfection of E. coli in urine simulant.

Journal Article Journal of applied electrochemistry · January 2019 AbstractWe report the development of novel modes of operation for electrochemical disinfection of E. coli in human urine simulant with an aim to minimize the energy required for disinfection. The system employs boron-doped diamond electrode ... Full text Cite

Electropermeabilization of nematode eggs for parasite deactivation.

Journal Article Journal of water, sanitation, and hygiene for development : a journal of the International Water Association · January 2019 The eggs of parasitic helminth worms are incredibly resilient - possessing the ability to survive changing environmental factors and exposure to chemical treatments - which has restricted the efficacy of wastewater sanitation. This research reports on the ... Full text Cite

Towards an off-grid fecal sludge treatment unit: demonstrating energy positive thermal treatment.

Journal Article Gates open research · January 2019 Background: There is an unmet demand for community-scale fecal sludge treatment units (FSTUs) that serve communities of between 1,000 and 50,000 people and are able to operate in non-sewered and off-grid environments. An emerging industry standard f ... Full text Cite

Prototype coded aperture miniature mass spectrometer for environmental sensing

Conference AQM 2019 - Air Quality Measurement Methods and Technology Conference 2019 · January 1, 2019 © 2019 Air and Waste Management Association. All rights reserved. In summary, this paper shows the design and initial performance characterization of a coded aperture miniature mass spectrometer for environmental sensing (CAMMS-ES). CAMMS-ES incorporates s ... Cite

Non-biological methods for phosphorus and nitrogen removal from wastewater: A gap analysis of reinvented-toilet technologies with respect to ISO 30500

Journal Article Gates Open Research · January 1, 2019 © 2019 Trotochaud L et al. The aims of the Reinvent the Toilet Challenge (RTTC) include creation of an off-the-grid sanitation system with operating costs of less than US$0.05 per user per day. Because of the small scale at which many reinvented toilets (R ... Full text Cite

Improving energy efficiency of electrochemical blackwater disinfection through sequential reduction of suspended solids and chemical oxygen demand

Journal Article · 2019 Onsite reuse of blackwater requires removal of considerable amounts of suspended solids and organic material in addition to inactivation of pathogens. Previously, we showed that electrochemical treatment could be used for effective pathogen inactivation in ... Full text Cite

Prototype coded aperture miniature mass spectrometer for environmental sensing

Conference AQM 2019 - Air Quality Measurement Methods and Technology Conference 2019 · January 1, 2019 In summary, this paper shows the design and initial performance characterization of a coded aperture miniature mass spectrometer for environmental sensing (CAMMS-ES). CAMMS-ES incorporates spatial aperture coding to break the throughput vs. resolution trad ... Cite

Non-biological methods for phosphorus and nitrogen removal from wastewater: A gap analysis of reinvented-toilet technologies with respect to ISO 30500.

Journal Article Gates open research · January 2019 The aims of the Reinvent the Toilet Challenge (RTTC) include creation of an off-the-grid sanitation system with operating costs of less than US$0.05 per user per day. Because of the small scale at which many reinvented toilets (RT) are intended to operate, ... Full text Cite

A granular activated carbon/electrochemical hybrid system for onsite treatment and reuse of blackwater.

Journal Article Water research · November 2018 Over 1/3 of the global population lacks access to improved sanitation, leading to disease, death, and impaired economic development. Our group is working to develop rapidly deployable, cost-effective, and sustainable solutions to this global problem that d ... Full text Cite

Improved blackwater disinfection using potentiodynamic methods with oxidized boron-doped diamond electrodes.

Journal Article Water research · September 2018 Electrochemical disinfection (ECD) has become an important blackwater disinfection technology. ECD is a promising solution for the 2 billion people without access to conventional sanitation practices and in areas deficient in basic utilities (e.g., sewers, ... Full text Cite

Proof of Concept Coded Aperture Miniature Mass Spectrometer Using a Cycloidal Sector Mass Analyzer, a Carbon Nanotube (CNT) Field Emission Electron Ionization Source, and an Array Detector.

Journal Article Journal of the American Society for Mass Spectrometry · February 2018 Despite many potential applications, miniature mass spectrometers have had limited adoption in the field due to the tradeoff between throughput and resolution that limits their performance relative to laboratory instruments. Recently, a solution to this tr ... Full text Cite

Improving energy efficiency of electrochemical blackwater disinfection through sequential reduction of suspended solids and chemical oxygen demand.

Journal Article Gates open research · January 2018 Onsite reuse of blackwater requires removal of considerable amounts of suspended solids and organic material in addition to inactivation of pathogens. Previously, we showed that electrochemical treatment could be used for effective pathogen inactivation in ... Full text Cite

A miniature electron ionization source fabricated using microelectromechanical systems (MEMS) with integrated carbon nanotube (CNT) field emission cathodes and low-temperature co-fired ceramics (LTCC)

Journal Article International Journal of Mass Spectrometry · November 1, 2017 The use of microelectromechanical systems (MEMS) components in miniature mass spectrometers is particularly attractive due to their small size and scalable manufacturing capability. Our group has pioneered the development of miniature electron ionization s ... Full text Cite

Electrochemical disinfection of repeatedly recycled blackwater in a free-standing, additive-free toilet.

Journal Article Water and environment journal : the journal · November 2017 Decentralized, energy-efficient waste water treatment technologies enabling water reuse are needed to sustainably address sanitation needs in water- and energy-scarce environments. Here, we describe the effects of repeated recycling of disinfected blackwat ... Full text Cite

Coded Apertures in Mass Spectrometry.

Journal Article Annual review of analytical chemistry (Palo Alto, Calif.) · June 2017 The use of coded apertures in mass spectrometry can break the trade-off between throughput and resolution that has historically plagued conventional instruments. Despite their very early stage of development, coded apertures have been shown to increase thr ... Full text Cite

Enhanced H2O2 Production at Reductive Potentials from Oxidized Boron-Doped Ultrananocrystalline Diamond Electrodes.

Journal Article ACS applied materials & interfaces · May 2017 This work investigates the surface chemistry of H2O2 generation on a boron-doped ultrananocrystalline diamond (BD-UNCD) electrode. It is motivated by the need to efficiently disinfect liquid waste in resource constrained environments ... Full text Cite

Integrating carbon nanotube forests into polysilicon MEMS: Growth kinetics, mechanisms, and adhesion

Journal Article Carbon · March 1, 2017 The growth of carbon nanotubes (CNTs) on polycrystalline silicon substrates was studied to improve the design of CNT field emission sources for microelectromechanical systems (MEMS) applications and vacuum microelectronic devices (VMDs). Microwave plasma-e ... Full text Cite

Improved Performance of Field Emission Vacuum Microelectronic Devices for Integrated Circuits

Journal Article IEEE Transactions on Electron Devices · September 1, 2016 The movement from discrete transistors to integrated silicon circuits led to the rapid evolution of microscale electronics, but there has been no equivalent transition for the vacuum tube transistor. Difficulty integrating devices at microscales has hinder ... Full text Cite

Development and field testing of a decentralized, self-contained toilet that converts human waste into burnable fuel and disinfected, reusable liquid

Conference WEFTEC 2016 - 89th Water Environment Federation Annual Technical Exhibition and Conference · January 1, 2016 Novel waste treatment solutions are being created for developing countries to meet the needs of the over 2.5 billion people without access to proper sanitation. RTI International is developing a toilet that will operate completely separate from the traditi ... Full text Cite

Chemical ionization mass spectrometry using carbon nanotube field emission electron sources.

Journal Article Journal of the American Society for Mass Spectrometry · November 2015 A novel chemical ionization (CI) source has been developed based on a carbon nanotube (CNT) field emission electron source. The CNT-based electron source was evaluated and compared with a standard filament thermionic electron source in a commercial explosi ... Full text Cite

Achieving Excellence in Graduate Research: A Guide for New Graduate Students.

Journal Article Advanced science (Weinheim, Baden-Wurttemberg, Germany) · October 2015 A mentoring guide for incoming graduate students has been developed to minimize the time spent reiterating general guidance and "norms" that need to be instilled in new graduate students. This allows principal investigators and senior researchers to ... Full text Cite

Order of Magnitude Signal Gain in Magnetic Sector Mass Spectrometry Via Aperture Coding.

Journal Article Journal of the American Society for Mass Spectrometry · September 2015 Miniaturizing instruments for spectroscopic applications requires the designer to confront a tradeoff between instrument resolution and instrument throughput [and associated signal-to-background-ratio (SBR)]. This work demonstrates a solution to this trade ... Full text Cite

Role of nanocrystalline domain size on the electrochemical double-layer capacitance of high edge density carbon nanostructures

Journal Article MRS Communications · June 1, 2015 Nanostructured carbon materials, especially activated carbon, carbon nanotubes, and graphene, have been widely studied for supercapacitor applications. To maximize the efficacy of these materials for electrochemical energy storage, a detailed understanding ... Full text Cite

Optimization of active manganese oxide electrodeposits using graphenated carbon nanotube electrodes for supercapacitors

Journal Article Chemistry of Materials · April 14, 2015 Graphenated carbon nanotubes (g-CNTs) were investigated as the electrode support in MnO2 composite cathodes for aqueous asymmetric supercapacitors. The electrode performance could be tuned by optimizing the density of graphene foliates on the g- ... Full text Cite

Eliminating proximity effects and improving transmission in field emission vacuum microelectronic devices for integrated circuits

Conference Technical Digest - International Electron Devices Meeting, IEDM · February 16, 2015 This work evaluates crosstalk and transmission efficiency in multi-integrated field emission vacuum microelectronic devices (FE-VMDs). Experimental evidence showed that proximity effects cannot be neglected, therefore indicating a need for additional contr ... Full text Cite

Two-dimensional aperture coding for magnetic sector mass spectrometry.

Journal Article Journal of the American Society for Mass Spectrometry · February 2015 In mass spectrometer design, there has been a historic belief that there exists a fundamental trade-off between instrument size, throughput, and resolution. When miniaturizing a traditional system, performance loss in either resolution or throughput would ... Full text Cite

Perspectives on the Growth of High Edge Density Carbon Nanostructures: Transitions from Vertically Oriented Graphene Nanosheets to Graphenated Carbon Nanotubes.

Journal Article The journal of physical chemistry. C, Nanomaterials and interfaces · July 2014 Insights into the growth of high edge density carbon nanostructures were achieved by a systematic parametric study of plasma-enhanced chemical vapor deposition (PECVD). Such structures are important for electrode performance in a variety of applications su ... Full text Cite

Diamond surface functionalization with biomimicry - Amine surface tether and thiol moiety for electrochemical sensors

Journal Article Applied Surface Science · May 15, 2014 The surface of conducting diamond was functionalized with a terminal thiol group that is capable of binding and detecting nitrogen-oxygen species. The functionalization process employed multiple steps starting with doped diamond films grown by plasma enhan ... Full text Cite

Evidence of yttrium silicate inclusions in YSZ-porcelain veneers.

Journal Article Journal of biomedical materials research. Part B, Applied biomaterials · April 2014 This report introduces the discovery of crystalline defects that can form in the porcelain veneering layer when in contact with yttria-stabilized zirconia (YSZ). The focus was on dental prostheses and understanding the defects that form in the YSZ/porcelai ... Full text Cite

Selected Topics on the Synthesis, Properties and Applications of Multiwalled Carbon Nanotubes.

Journal Article Diamond and related materials · February 2014 In summary, MWCNTs have been examined for a variety of electronic applications due to their unique structure and chemistry. Electrodes for field emission, energy and sensor applications hold particular interest. MWCNTs provide a very high surface area, rel ... Full text Cite

Platform for integrated vacuum microelectronic circuits

Conference IEEE International Vacuum Electronics Conference, IVEC 2014 · January 1, 2014 Vacuum devices are preferred to solid-state for applications requiring radiation stability, a wide range in operating temperature, or high power at high frequency. However, difficulties associated with integrating these devices on the microscale have limit ... Full text Cite

Disinfection of E. coli contaminated urine using boron-doped diamond electrodes

Journal Article Journal of the Electrochemical Society · January 1, 2014 We report the development of an electrochemical disinfection system for human urine, which does not require the addition of any external water or chemical reagents. It is designed to minimize energy consumption so that it may be powered from point-of-use s ... Full text Cite

Electrochemical oxidation of phenol using boron doped diamond electrodes

Conference ECS Transactions · January 1, 2014 The oxidation of phenol is compared for two different boron doped diamond (BDD) electrodes; a niobium supported BDD planar electrode and a BDD coated Ti mesh. Raman spectroscopy and cyclic voltammetry were used to compare the two electrodes. Continuous oxi ... Full text Cite

Thermoelectric energy harvesting for a solid waste processing toilet

Conference Proceedings of SPIE - The International Society for Optical Engineering · January 1, 2014 Over 2.5 billion people do not have access to safe and effective sanitation. Without a sanitary sewer infrastructure, self-contained modular systems can provide solutions for these people in the developing world and remote areas. Our team is building a bet ... Full text Cite

Growth and characterization of graphenated carbon nanotubes for high charge density applications

Conference ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY · September 8, 2013 Link to item Cite

Fracture toughness improvements of dental ceramic through use of yttria-stabilized zirconia (YSZ) thin-film coatings.

Journal Article Dental materials : official publication of the Academy of Dental Materials · August 2013 ObjectivesThe aim of this study was to evaluate strengthening mechanisms of yttria-stabilized zirconia (YSZ) thin film coatings as a viable method for improving fracture toughness of all-ceramic dental restorations.MethodsBars (2mm×2mm×15 ... Full text Cite

Cu(ii)/Cu(0) electrocatalyzed CO2 and H2O splitting

Journal Article Energy and Environmental Science · March 1, 2013 In an earlier report we showed that in concentrated carbonate/bicarbonate solutions, simple Cu(ii) salts are highly reactive as water oxidation electro-catalysts. We report here, based on earlier results in the literature, that Cu(0) films on a boron-doped ... Full text Cite

Electrochemical disinfection of human urine for water-free and additive-free toilets using boron-doped diamond electrodes

Journal Article ECS Transactions · January 1, 2013 We report the development of an electrochemical disinfection system for human urine, which does not require the addition of any external water or chemical reagents. It is designed to minimize energy consumption so that it may derive its energy from solar p ... Full text Cite

Electrochemical charge storage properties of vertically aligned carbon nanotube films: Effects of thermal oxidation

Journal Article Journal of Physical Chemistry C · September 13, 2012 Vertically aligned carbon nanotube (VACNT) films were synthesized and investigated in vitro for their potential use as a neural stimulation electrode. Materials and electrochemical (EC) characterization (cyclic voltammetry, electrochemical impedance spectr ... Full text Cite

Modeling operational modes of a bipolar vacuum microelectronic device

Journal Article IEEE Electron Device Letters · August 27, 2012 Vacuum microelectronic devices (VMDs) designed for bipolar charge operation hold great promise for applications in radiation-intensive and high-temperature environments. This novel class of devices was first realized in a microelectromechanical platform le ... Full text Cite

Nanoelectronics: Nothing is like a vacuum.

Journal Article Nature nanotechnology · August 2012 Full text Cite

Surface fluorination of zirconia: adhesive bond strength comparison to commercial primers.

Journal Article Dental materials : official publication of the Academy of Dental Materials · June 2012 ObjectiveThis study evaluated contact angle and shear bond strength of three commercial zirconia primers and compared them to a recently developed fluorination pre-treatment. Earlier investigations reported that plasma fluorinated zirconia modifie ... Full text Cite

Three-dimensional arrays of graphenated carbon nanotubes

Journal Article Journal of Materials Research · April 14, 2012 Graphene and carbon nanotubes (CNTs) are fascinating materials, both scientifically and technologically, due to their exceptional properties and potential use in applications ranging from high-frequency electronics to energy storage devices. This manuscrip ... Full text Cite

Carbon nanostructures: A morphological classification for charge density optimization

Journal Article Diamond and Related Materials · March 1, 2012 Nanostructured carbons offer great promise in numerous electrode applications due to their high surface area and area specific capacitance. With the growing importance of energy applications in particular, a need has emerged to characterize the various for ... Full text Cite

A compact and multichannel optical biosensor based on a wavelength interrogated input grating coupler

Journal Article Sensors and Actuators, B: Chemical · January 3, 2012 The design, fabrication and characterization of a compact optical biosensor based on an input grating coupler are presented. The sensor device consists of a waveguide-integrated single grating structure. The optical reader is based on the use of a largely ... Full text Cite

Electrochemical oxidation of organic compounds using boron-doped diamond electrodes

Conference ECS Transactions · January 1, 2012 Boron-doped diamond (BDD) electrodes prepared by chemical vapor deposition were used to determine if phenol could be oxidized to CO2 and if biofilms could be oxidized and "cleaned" from a surface. Cyclic voltammetry showed that phenol and biofilms were ele ... Full text Cite

Triple blind fractography study of yttria-stabilized zirconia thin-film-modified porcelain

Conference Ceramic Transactions · January 1, 2012 Objective: To determine if experience and fractography methodology of examiners results in differences in fracture toughness estimation of thin-film modified glass-ceramic Methods: Glass-ceramic blocks (Empress CAD, Ivoclar Vivadent, Schaan, Liechtenstein) ... Full text Cite

Graphenated carbon nanotubes for enhanced electrochemical double layer capacitor performance

Journal Article Applied Physics Letters · October 2011 This letter reports on nucleation and growth of graphene foliates protruding from the sidewalls of aligned carbon nanotubes (CNTs) and their impact on the electrochemical double-layer capacitance. Arrays of CNTs were grown for different time intervals, res ... Open Access Cite

Characterization of plasma fluorinated zirconia for dental applications by X-ray photoelectron spectroscopy

Journal Article Applied Surface Science · September 15, 2011 This paper discusses fluorination of biomedical-grade yttria-stabilized zirconia (YSZ) by sulfur hexafluoride plasma treatment and characterization of near-surface chemistry products by X-ray photoelectron spectroscopy (XPS). Deconvolution of the Zr 3d and ... Full text Cite

A Bipolar Vacuum Microelectronic Device

Journal Article Ieee Transactions on Electron Devices · September 2011 Cite

A novel array chip to monitor in situ composite degradation using electrochemical impedance spectroscopy.

Journal Article Dental materials : official publication of the Academy of Dental Materials · August 2011 ObjectivesThis paper presents a novel array-chip technology used to monitor the physical properties of dental composites in situ. The DECAY chip (Degradation via Electrochemical Array) leverages microfabrication techniques to construct a uniform a ... Full text Cite

Long-term microtensile bond strength of surface modified zirconia.

Journal Article Dental materials : official publication of the Academy of Dental Materials · August 2011 ObjectiveTo compare long-term microtensile bond strength of zirconia, surface-modified via a novel treatment, to current surface conditioning methods for zirconia, when resin bonded to dental composite.MethodsTwo ProCAD (porcelain) and 10 ... Full text Cite

Tunable wavelength interrogated sensor platform (TWIST) for point-of-care diagnostics of infectious diseases

Conference Proceedings of SPIE - The International Society for Optical Engineering · July 6, 2011 The TWIST platform is an optical evanescent wave sensor which enables a label-free immunoassay-based portable instrument. The approach is based on input grating coupler sensors serving as functionalized sensing devices. Binding of the target analyte to the ... Full text Cite

Enhanced bonding between YSZ surfaces using a gas-phase fluorination pretreatment.

Journal Article Journal of biomedical materials research. Part B, Applied biomaterials · July 2011 The present investigation focuses on the surface modification, via gas-phase fluorination process, of yttria- stabilized zirconia (YSZ) to increase its wettability and chemical bonding directly to acrylate-based resin cements. YSZ plates and cylinders, as- ... Full text Cite

Development of a novel surface modification for improved bonding to zirconia.

Journal Article Dental materials : official publication of the Academy of Dental Materials · May 2011 ObjectiveThis report presents a novel pretreatment technique, whereby the zirconia surface is converted to a more reactive zirconium oxyfluoride, enabling improved chemical bonding to other dental substrates via conventional silanation approaches. ... Full text Cite

Adhesion/cementation to zirconia and other non-silicate ceramics: where are we now?

Journal Article Dental materials : official publication of the Academy of Dental Materials · January 2011 Non-silicate ceramics, especially zirconia, have become a topic of great interest in the field of prosthetic and implant dentistry. A clinical problem with use of zirconia-based components is the difficulty in achieving suitable adhesion with intended synt ... Full text Cite

The effect of gold on platinum oxidation in homogeneous Au-Pt electrocatalysts

Journal Article Applied Surface Science · December 2010 Cite

Analysis of 3-panel and 4-panel microscale ionization sources

Journal Article Journal of Applied Physics · June 2010 Open Access Cite

Nanoimprint lithography fabrication of waveguide-integrated optical gratings with inexpensive stamps

Journal Article Microelectronic Engineering · January 1, 2010 We demonstrate that a replica grating can be effectively used as an inexpensive stamp for nanoimprint lithography to pattern diffractive optical couplers integrated with planar optical waveguides. Imprinted grating patterns were integrated with silicon oxy ... Full text Cite

Zirconia-parylene multilayer thin films for enhanced fracture resistance of dental ceramics.

Conference Proceedings of the Institution of Mechanical Engineers. Part H, Journal of engineering in medicine · October 2009 Recent research has shown that the application of specific thin films can enhance the material properties of a laminate construct. In this study, the effect of different mono/multilayered films on the strength of a ceramic specimen is demonstrated. It is w ... Full text Cite

Surface modification for enhanced silanation of zirconia ceramics.

Journal Article Dental materials : official publication of the Academy of Dental Materials · September 2009 ObjectiveThe overall goal of this research was to develop a practical method to chemically modify the surface of high strength dental ceramics (i.e. zirconia) to facilitate viable, robust adhesive bonding using commercially available silanes and r ... Full text Cite

Wavelength interrogation of optical waveguide biosensors in the input grating coupler configuration

Conference Proceedings of SPIE - The International Society for Optical Engineering · June 15, 2009 A planar optical waveguide with an input grating coupler was used as an affinity-based biodetection device. Nanoimprint lithography was used to integrate the grating patterns with low loss silicon oxynitride thin-film waveguides. A widely tunable laser sou ... Full text Cite

Simulation and testing of a lateral, microfabricated electron-impact ion source

Journal Article Applied Physics Letters · January 2009 Cite

Dynamic fatigue behavior of dental porcelain modified by surface deposition of a YSZ thin film.

Journal Article Journal of prosthodontics : official journal of the American College of Prosthodontists · October 2008 PurposeThe objective of this study was to evaluate the basic fatigue parameters of a dental porcelain modified by deposition of a yttria-stabilized zirconia (YSZ) thin film and to compare the data to that of an unmodified control.MethodsT ... Full text Cite

Artificial eyelid dynamic aperture optical arrays for large scale coding elements with application in visible to MWIR

Conference Proceedings of SPIE - The International Society for Optical Engineering · September 29, 2008 The use of coded apertures in a large area MWIR system introduces a number of difficulties including the effects of diffraction and other distortions not observed in shorter wavelength systems. A new approach is being developed that addresses the effects o ... Full text Cite

High voltage MEMS platform for fully integrated, on-chip, vacuum electronic devices

Journal Article 2008 IEEE International Vacuum Electronics Conference, IVEC with 9th IEEE International Vacuum Electron Sources Conference, IVESC · September 15, 2008 We demonstrate a fully integrated, on-chip, vacuum microtriode capable of handling voltages up to 800 V. The ability to operate at such high voltages is achieved by the addition of a 10 μm-thick silicon dioxide layer to the device. The device is fabricated ... Full text Cite

Alloying effects of cosputtered gold-platinum thin films on the oxygen reduction reaction in acidic electrolyte

Journal Article Journal of the Electrochemical Society · July 11, 2008 A better understanding of the effects of alloying Pt with Au on the oxygen reduction reaction (ORR) was achieved in this study. Recent investigations of carbon-supported Au-Pt nanoparticle catalysts have shown enhanced response for the ORR with respect to ... Full text Cite

High voltage microelectromechanical systems platform for fully integrated, on-chip, vacuum electronic devices

Journal Article Applied Physics Letters · June 2008 We demonstrate a fully integrated, on-chip, vacuum microtriode capable of handling voltages up to 800 V. The ability to operate at such high voltages is achieved by the addition of a 10 mu m thick silicon dioxide layer to the device. The device is fabricat ... Cite

Wavelength interrogation of grating-based optical biosensors in the input coupler configuration

Journal Article Sensors and Actuators, B: Chemical · May 14, 2008 A planar optical waveguide with an input grating coupler was used as a label-free biodetection device. Nanoimprint lithography was used to integrate the grating patterns with low loss silicon oxynitride thin film waveguides. A widely tunable laser source a ... Full text Cite

Effect of film chemistry on refractive index of plasma-enhanced chemical vapor deposited silicon oxynitride films: A correlative study

Journal Article Journal of Materials Research · May 1, 2008 Thick SiOxNy films were deposited by radiofrequency (rf) plasma chemical vapor deposition using silane (SiH4) and nitrous oxide (N2O) source gases. The influence of deposition conditions of gas flow ratio, rf plasma mixed-frequency ratio (100 kHz, 13.56 MH ... Full text Cite

A novel ion source and detector for a miniature mass spectrometer

Journal Article Proceedings of IEEE Sensors · December 1, 2007 Due to its flexibility and sensitivity, mass spectrometry is a preferred sensing method for applications ranging from explosives detection to air quality monitoring. The key functional elements of a mass spectrometer are ionization, mass separation, and io ... Full text Cite

Charge transfer equilibria between diamond and an aqueous oxygen electrochemical redox couple.

Journal Article Science (New York, N.Y.) · November 2007 Undoped, high-quality diamond is, under almost all circumstances, one of the best insulators known. However, diamond covered with chemically bound hydrogen shows a pronounced conductivity when exposed to air. This conductivity arises from positive-charge c ... Full text Cite

Effect of YSZ thin film coating thickness on the strength of a ceramic substrate.

Journal Article Journal of biomedical materials research. Part B, Applied biomaterials · November 2007 Although ceramics are used for many different biomedical applications they are brittle materials that can be compromised by surface defects when under stress. The objective of this study was to evaluate the effect of surface modification with an yttria-sta ... Full text Cite

Microfabrication of fine-pitch high aspect ratio Faraday cup arrays in silicon

Journal Article Sensors and Actuators, A: Physical · July 4, 2007 Dense one-dimensional arrays of high aspect ratio Faraday cups have been microfabricated for application as position sensitive charged particle detectors. The method developed to fabricate these Faraday cup arrays utilizes deep reactive ion etching (DRIE) ... Full text Cite

Dynamic fatigue and strength characterization of three ceramic materials.

Journal Article Journal of materials science. Materials in medicine · June 2007 Fracture strength and fatigue parameters of three ceramic materials submitted to dynamic fatigue were evaluated. A machinable leucite-reinforced dental ceramic, aluminum oxide, and yttria-stabilized zirconia (YSZ) were tested. The inert strength of the mat ... Full text Cite

Optical waveguide biosensor based on two-dimensional diffractive elements obtained by nano-imprint lithography

Conference Proceedings of SPIE - The International Society for Optical Engineering · May 24, 2007 This work focuses on the effects of custom-designed, two-dimensional grating structures on the sensitivity of optical waveguides biosensors in the input grating coupler configuration. Calculations suggest that suitably designed diffractive structures with ... Full text Cite

Evidence of stress-induced tetragonal-to-monoclinic phase transformation during sputter deposition of yttria-stabilized zirconia

Journal Article Journal of Materials Research · April 1, 2007 Partially stabilized zirconia (PSZ) has been studied extensively, due to its high-temperature stability and stress-induced tetragonal (T)-to-monoclinic (M) martensitic phase transformation. This T ⇒ M phase transformation has been well-documented for bulk ... Full text Cite

Ceramics for restorative dentistry: Critical aspects for fracture and fatigue resistance

Journal Article Materials Science and Engineering C · April 1, 2007 Development of non-metallic restorative materials is a high priority due to biocompatibility issues and environmental concerns associated with metals waste and disposal. Ceramics are an ideal candidate for replacing metal-based restorative materials. Ceram ... Full text Cite

On-chip electron-impact ion source using carbon nanotube field emitters

Journal Article Applied Physics Letters · March 2007 A lateral on-chip electron-impact ion source utilizing a carbon nanotube field emission electron source was fabricated and characterized. The device consists of a cathode with aligned carbon nanotubes, a control grid, and an ion collector electrode. The el ... Full text Open Access Link to item Cite

Dynamic aperture optical arrays based on polymeric MEMS actuators for large scale coding elements with application in visible to MWIR

Journal Article Proceedings of SPIE - The International Society for Optical Engineering · 2007 Extension of coded apertures to the MWIR introduces the effects of diffraction and other distortions not observed in shorter wavelength systems. A new approach is being developed under the DARPA/SPO funded LACOSTE (Large Area Coverage Optical search-while ... Full text Cite

Alloying effects of co-sputtered gold-platinum thin films on the oxygen reduction reaction in acidic electrolyte

Journal Article ECS Transactions · January 1, 2007 Co-sputtering was utilized to form metastable solid solution Au/Pt alloy films across the entire range of possible compositions. Homogeneous mixing was achieved without nanoparticle geometries, thereby isolating the effects of alloying from nanoscale size ... Full text Cite

High voltage compatible micromachined vacuum electronic devices with carbon nanotube cold cathodes

Journal Article 2006 IEEE International Vacuum Electronics Conference held jointly with 2006 IEEE International Vacuum Electron Sources, IVEC/IVESC 2006 · December 1, 2006 Previously, Bower et al. [1] demonstrated a microfabricated vacuum microtriode with an integrated carbon nanotube field emission cathode. One of the main limitations of the microtriode was the inadequate device insulation which suffered from leakage curren ... Cite

Novel grating-based optical waveguide device for sensor applications

Conference Proceedings of SPIE - The International Society for Optical Engineering · August 23, 2006 Grating-based optical waveguide devices offer label-free biodetection capabilities relying on optical response to adsorption of analytes and corresponding changes of refractive index. Various configurations of this measurement approach were explored with t ... Full text Cite

Stress evolution as a function of substrate bias in rf magnetron sputtered yttria-stabilized zirconia films

Journal Article Journal of Vacuum Science and Technology A: Vacuum, Surfaces and Films · July 1, 2006 An increase in compressive stress was observed in rf magnetron sputtered yttria-stabilized zirconia thin films upon exposure to ambient conditions (25°C and 75% relative humidity). This increase was attributed to absorption of water molecules into intergra ... Full text Cite

Novel optical-waveguide sensing platform based on input grating coupler

Conference Proceedings of SPIE - The International Society for Optical Engineering · May 25, 2006 Silicon oxynitride optical waveguides with a grating coupler were used for a label-free detection approach that measures the change of refractive index at the grating surface. Two approaches were used for the grating fabrication: (i) commercially available ... Full text Cite

Zirconia thin-films for toughened ceramics

Conference Proceedings of the International Conference on Manufacturing Science and Engineering · January 1, 2006 Partially-stabilized zirconia (PSZ) has been studied extensively, due to its high temperature stability and stress-induced tetragonal to monoclinic phase transformation, which can elicit enhanced fracture resistance. Applications include thermal barriers, ... Full text Cite

Effect of growth parameters on refractive index and film composition of plasma enhanced chemical vapor deposition silicon oxynitride films

Journal Article Materials Research Society Symposium Proceedings · December 19, 2005 The importance of silicon oxynitride (SiOxNy) for optoelectronic device applications is ever increasing owing to its tunable refractive index. In this research, the influence of deposition conditions on film properties, correlated with film composition and ... Cite

Verification of the O-Si-N complex in plasma-enhanced chemical vapor deposition silicon oxynitride films

Journal Article Applied Physics Letters · December 1, 2005 Silicon oxynitride films were deposited using a plasma-enhanced chemical vapor deposition process. The bond configurations of the constituent atoms in the deposited film were analyzed using x-ray photoelectron spectroscopy. Analysis of the Si 2p spectra sh ... Full text Cite

Improved optical loss characteristics of PECVD silicon oxynitride films using low frequency plasma

Journal Article Materials Research Society Symposium Proceedings · December 1, 2005 With the continued growth of photonics, silicon oxynitride (SiO xN y) is becoming a popular material for optoelectronic applications owing to its large tunable refractive index. However, with the increase in refractive index, these films tend to show poor ... Cite

Evaluation of crystallinity and film stress in yttria-stabilized zirconia thin films

Journal Article Journal of Vacuum Science and Technology A: Vacuum, Surfaces and Films · September 1, 2005 Yttria (3 mol %)-stabilized zirconia (YSZ) thin films were deposited using radio frequency (rf) magnetron sputtering. The YSZ thin films were deposited over a range of temperatures (22-300 °C), pressures (5-25 mTorr), and gas compositions (ArO ratio). Init ... Full text Cite

Template-directed assembly on an ordered microsphere array.

Journal Article Langmuir : the ACS journal of surfaces and colloids · May 2005 We investigated the capability of an ordered array of microspheres to act as a template for deposition and ordering of a subsequent layer of microspheres. An evaporation-based technique was used to deposit monolayers of large colloidal spheres. A novel tec ... Full text Cite

Advanced processing techniques for through-wafer interconnects

Conference Journal of Vacuum Science and Technology B: Microelectronics and Nanometer Structures · January 1, 2004 Full text Cite

Investigation of the layer-by-layer assembly of colloid crystals on a templated substrate

Conference Materials Research Society Symposium Proceedings · January 1, 2004 We investigated the fabrication of a 3D colloid crystal assembled in a layer-by-layer fashion on a template substrate. This method of assembling an ordered structure offers flexibility in the choice of crystal orientation, because of the template, and the ... Full text Cite

The effect of deposition parameters on the properties of yttria-stabilized zirconia thin films

Journal Article Thin Solid Films · November 24, 2003 Yttria-stabilized zirconia (YSZ) films were deposited by RF magnetron sputtering in order to examine the effects of sputtering conditions on the properties of the resulting thin-films. X-ray diffraction (XRD), Rutherford backscattering spectroscopy (RBS) a ... Full text Cite

Photonic crystal composites with reversible high-frequency stop band shifts

Journal Article Advanced Materials · May 2, 2003 The photonic crystal composites with reversible high-frequency stop band shifts were studied. Two forms of manipulating spherical colloidal particles for the generation of photonic crystals were used. A report on a procedure that allowed for the tailoring ... Full text Cite

Solvent-induced morphology in nano-structures

Chapter · January 1, 2003 Solvent-induced phenomena sometimes have undesirable influences on the morphology of carefully designed nanomaterials. The chapter basically describes the morphology of two seemingly unrelated nano-structures-arrays of multi-walled carbon nanotubes and sol ... Full text Cite

Transmission electron microscopy study of the structure of radio frequency sputter-deposited yttria-stabilized zirconia thin films

Journal Article Journal of Materials Research · January 1, 2003 Transmission electron microscopy (TEM) was used to investigate the structural properties of sputter-deposited yttria-stabilized zirconia (YSZ) thin films. YSZ films were deposited over a range of temperatures and background oxygen levels. Additionally, a m ... Full text Cite

Integration of photonic bandgap composites with piezoelectric actuators for rejection wavelength tuning

Conference Proceedings of SPIE - The International Society for Optical Engineering · December 1, 2002 Physically robust photonic bandgap (PEG) composites based on electrostatically stabilized polymeric colloidal particles are presented. The glass transition (Tg) of the composites can be varied over a large temperature range through the selection of the mon ... Full text Cite

Effect of deposition interruption and substrate bias on the structure of sputter-deposited yttria-stabilized zirconia thin films

Journal Article Journal of Vacuum Science and Technology A: Vacuum, Surfaces and Films · September 1, 2002 The effect of deposition interruption and substrate bias on the structure of sputter-deposited yttria-stabilized zirconia thin films was discussed. The use of a periodic substrate bias was found to produce a laminate structure with alternating layers of di ... Full text Cite

Finite element analysis on dental implant-supported prostheses without passive fit.

Journal Article Journal of prosthodontics : official journal of the American College of Prosthodontists · March 2002 PurposeThe purpose of this study is to use finite element analysis to investigate the effect of misfit prostheses, cantilever prostheses, and various occlusal forces on the stress distribution in the prostheses, implant components, and surrounding ... Full text Cite

Finite element analysis on dental implant–supported prostheses without passive fit

Journal Article Journal of Prosthodontics · March 2002 PurposeThe purpose of this study is to use finite element analysis to investigate the effect of misfit prostheses, cantilever prostheses, and various occlusal forces on the stress di ... Full text Cite

Wafer bonding of diamond films to silicon for silicon-on-insulator technology

Journal Article Materials Research Society Symposium - Proceedings · January 1, 2002 Polycrystalline diamond films previously grown on silicon were polished to an RMS roughness of 15 nm and bonded to the silicon in a dedicated ultrahigh vacuum bonding chamber. Successful bonding under a uniaxial mechanical stress of 32 MPa was observed at ... Cite

Direct fusion bonding of silicon to polycrystalline diamond

Journal Article Diamond and Related Materials · 2002 High temperature fusion of silicon to diamond is reported. Polished, randomly oriented diamond films and unpolished (100) highly oriented diamond films were bonded to single-side polished (100) silicon in a dedicated ultrahigh vacuum bonding apparatus. Dir ... Full text Link to item Cite

Electrochemical Oxidation of Phenol Using Boron-Doped Diamond Electrodes

Journal Article Journal of the Electrochemical Society · July 1, 2001 Boron-doped diamond electrodes prepared by chemical vapor deposition were used to determine if phenol could be oxidized to CO 2. Cyclic voltammetry showed that phenol was oxidized by the diamond electrodes and remained electroactive after multiple cycles. ... Full text Cite

Observation of multiple nearly monoenergetic electron production by heated pyroelectric crystals in ambient gas

Journal Article Applied Physics Letters · February 19, 2001 Multiple production of nearly monoenergetic electrons at a given pyroelectric crystal surface charge density is observed on cooling or heating the crystal in ambient gas. Typically, the + z base of a 5 mm diam×5 mm crystal of LiNbO3 is heated to 100 °C and ... Full text Cite

Processing techniques for vertical interconnects

Conference 2001 International Semiconductor Device Research Symposium, ISDRS 2001 - Proceedings · January 1, 2001 Processing techniques that address the interconnect issues required for fabrication of deep sub-micron electronic devices and for three-dimensional (3D) integration of these components will be described. As the interconnect density increases, alternate met ... Full text Cite

Synthesis of carbon, silicon, and boron-nitride nanostructures via microwave plasma enhanced chemical vapor deposition

Journal Article Materials Research Society Symposium - Proceedings · January 1, 2001 Carbon, silicon nitride and boron nitride nanostructures were synthesized using microwave plasma enhanced chemical vapor deposition. Both scanning and transmission electron microscopies and x-ray diffraction were used to observe the morphology and structur ... Cite

Nucleation and growth of silicon nitride nanoneedles using microwave plasma heating

Journal Article Journal of Materials Research · January 1, 2001 We report on needlelike silicon nitride nanowires grown on silicon using ammonia microwave plasma heating. Scanning electron microscope reveals that the nanoneedles are either straight, slightly bent, or kinked with sharp tips. Transmission electron micros ... Full text Cite

Aligned carbon nanotubes via microwave plasma enhanced chemical vapor deposition

Conference Materials Research Society Symposium - Proceedings · December 3, 2000 Aligned multi-wall carbon nanotubes have been grown on silicon substrates by microwave plasma enhanced chemical vapor deposition using methane/ammonia mixtures. The concentration ratio of methane/ammonia in addition to substrate temperature was varied. The ... Cite

Deposition of aligned bamboo-like carbon nanotubes via microwave plasma enhanced chemical vapor deposition

Journal Article Journal of Applied Physics · November 15, 2000 Aligned multiwall carbon nanotubes have been grown on silicon substrates by microwave plasma enhanced chemical vapor deposition using methane/ammonia mixtures. Scanning electron microscopy shows that the nanotubes are well aligned with high aspect ratio an ... Full text Cite

Mechanical properties of a dental ceramic coated by RF magnetron sputtering.

Journal Article Journal of biomedical materials research · September 2000 Metal and ceramic thin film coatings were deposited onto a dental ceramic via radio frequency (RF) magnetron sputtering. The objectives of the study were to determine if a coherent interface could be produced between the coating and the substrate and if th ... Full text Cite

Application of carbon nanotubes as electrodes in gas discharge tubes

Journal Article Applied Physics Letters · March 27, 2000 Gas-tube protector units are used in telecom network interface device boxes and central office switching gears to provide protection from lightning and alternating current power cross faults on the telecom network. Current gas discharge tube (GDT) protecto ... Full text Cite

Diamond field-effect transistors

Chapter · January 1, 1998 Metal-oxide-serniconductor field-effect transistors (FETs) have been fabricated using B-doped diamond thin films deposited on polycrystalline, (100) highly-oriented, and single crystal diamond insulating substrates. Diamond films were grown using a microwa ... Full text Cite

Comparison of external and internal planar radio frequency antennae for inductively coupled plasma

Journal Article Review of Scientific Instruments · January 1, 1997 Radio frequency (rf) antennae, coated with glass, were inductively coupled to an Ar plasma inside the processing chamber. Coupling efficiency η and electron density Ne were measured for moderate pressures (0.1-200 T) and rf power (10-2000 W). Decreasing th ... Full text Cite

Heteroepitaxial nucleation of diamond

Conference Materials Research Society Symposium - Proceedings · January 1, 1996 The heteroepitaxial nucleation and eventual growth of large area single crystal diamond films has long eluded researchers interested in tapping it's many enabling properties, specifically in the field of active electronics. The uncertainty surrounding the ... Cite

Bias induced diamond nucleation studies on refractory metal substrates

Journal Article Journal of Applied Physics · December 1, 1995 The carbide forming nature of the substrate appears to be an important property when performing bias-enhanced nucleation (BEN); therefore, various refractory metals were studied since they are known carbide formers. Nucleation densities approaching 1×1010/ ... Full text Open Access Cite

Diamond deposition using a planar radio frequency inductively coupled plasma

Journal Article Applied Physics Letters · December 1, 1995 A planar radio frequency inductively coupled plasma has been used to deposit diamond onto scratched silicon. This plasma source has been developed recently for use in large area semiconductor processing and holds promise as a method for scale up of diamond ... Full text Cite

Comparison of silicon, nickel, and nickel silicide (Ni3Si) as substrates for epitaxial diamond growth

Journal Article Surface Science · July 10, 1995 We carried out experimental and theoretical studies aimed at probing interface interactions of diamond with Si, Ni, and Ni3Si substrates. Oriented diamond films deposited on (100) silicon were characterized by polar Raman, polar XRD, and cross-sectional HR ... Full text Cite

Investigation of the process factor space on bias-enhanced nucleation of diamond on silicon

Journal Article Thin Solid Films · June 1, 1995 The influence of the process parameters on bias-enhanced nucleation of diamond on silicon was studied. When low pressures (< 15 Torr) and/or high bias voltages (more than 350 V d.c.) were used, no significant diamond nucleation was observed; in some cases ... Full text Cite

Some effects of silicon substrate roughness on the growth of highly oriented 〈100〉 diamond films

Journal Article Diamond and Related Materials · April 15, 1995 Highly oriented, 〈100〉-textured diamond films have been successfully grown on pristine silicon substrates using bias-enhanced nucleation techniques. This paper describes the characteristics of a highly oriented film deposited on the rough, as-cut, undersid ... Full text Cite

Field emission characteristics of diamond coated silicon field emitters

Journal Article Journal of Vacuum Science and Technology B: Microelectronics and Nanometer Structures · March 1, 1995 Single crystal silicon field emitters have been modified by surface deposition of diamond using bias-enhanced microwave plasma chemical vapor deposition. Polycrystalline diamond with a high nucleation density (1010/cm2) and small grain size (<20 nm) was ac ... Full text Cite

Assessing polar and azimuthal correlations for an oriented mosaic of (001) diamond crystallites on (001) silicon

Journal Article Diamond and Related Materials · January 1, 1995 The heteroepitaxial growth of diamond films on (001) silicon by bias-enhanced, microwave-assisted chemical vapor deposition leads to a mosaic of highly oriented crystallites. The majority of crystallites adopt a "cube-on-cube" orientation (diamond{hkl} ∥si ... Full text Cite

Nucleation and selected area deposition of diamond by biased hot filament chemical vapor deposition

Journal Article Journal of Materials Research · January 1, 1995 This paper describes a process for uniformly enhancing the nucleation density of diamond films on silicon (Si) substrates via dc-biased hot filament chemical vapor deposition (HFCVD). The Si substrate was negatively biased and the tungsten (W) filaments we ... Full text Cite

Positive identification of the ubiquitous triangular defect on the (100) faces of vapor-grown diamond

Journal Article Journal of Applied Physics · December 1, 1994 Scanning tunneling microscopy and atomic force microscopy were used to index the faces and orientation of the sloping triangular defect which often appears on the {100} surfaces of chemical-vapor-deposited diamond. These features were confirmed to be 〈111〉 ... Full text Cite

Highly oriented diamond films on Si: growth, characterization, and devices

Conference Proceedings of SPIE - The International Society for Optical Engineering · December 1, 1994 Highly oriented, (100) textured diamond films have been grown on single-crystal Si substrates via microwave plasma enhanced chemical vapor deposition. A multistep deposition process including bias-enhanced nucleation and textured growth was used to obtain ... Cite

Imaging of boron dopant in highly oriented diamond films by cathodoluminescence in a transmission electron microscope

Journal Article Applied Physics Letters · December 1, 1994 Boron-doped, highly oriented, (100) textured diamond films have been examined by cathodoluminescence in a transmission electron microscope to assess the distribution of the defects and boron dopant within the films. Dislocation-related luminescence, which ... Full text Cite

Electron emission from diamond coated silicon field emitters

Journal Article Applied Physics Letters · December 1, 1994 Polycrystalline diamond thin films have been formed on single crystal silicon field emitters using bias-enhanced nucleation in a microwave plasma chemical vapor deposition system. A diamond nucleation density greater than 1010/cm2 with small grain sizes (< ... Full text Cite

Epitaxial nucleation, growth and characterization of highly oriented, (100)-textured diamond films on silicon

Journal Article Diamond and Related Materials · January 1, 1994 Growth of highly oriented, (100)-textured diamond films has been achieved through a multistep growth process which included biasenhanced nucleation and textured growth. The grain misorientation was analyzed by polar X-ray diffraction, electron diffraction ... Full text Cite

Cathodoluminescence studies of oriented diamond films

Journal Article Diamond and Related Materials · January 1, 1994 Transport properties of highly oriented diamong films have shown a marked improvement over random polycrystalline material. Scanning cathodoluminescence microscopy has been used to determine the type of defects present in oriented films and the way in whic ... Full text Cite

Diamond field-effect transistors

Conference Materials Research Society Symposium - Proceedings · January 1, 1994 Metal-oxide-semiconductor field-effect transistors (FETs) have been fabricated using B-doped diamond thin films deposited on polycrystalline, (100) highly-oriented, and single crystal diamond insulating substrates. Diamond films were grown using a microwav ... Full text Cite

The effect of substrate material on bias-enhanced diamond nucleation

Journal Article Diamond and Related Materials · January 1, 1994 Diamond has been deposited on polycrystalline copper substrates via bias-enhanced nucleation, a pre-treatment technique to promote nucleation in which a negative potential is applied to the substrate. The maximum nucleation density of the diamond on the co ... Full text Cite

Investigation of the low angle grain boundaries in highly oriented diamond films via transmission electron microscopy

Journal Article Journal of Materials Research · January 1, 1994 Highly oriented diamond thin films grown on silicon via microwave plasma chemical vapor deposition were examined by transmission electron microscopy. In the plan view, defects appearing at the grain boundary were easily observed. (100) faceted grains that ... Full text Cite

Diamond nucleation studies on refractory metals and nickel

Journal Article Materials Research Society Symposium - Proceedings · January 1, 1994 Diamond nucleation has been investigated on a variety of potential heteroepitaxial substrate materials. Previous work in this laboratory has demonstrated heteroepitaxial nucleation on both Si and SiC substrates via bias-enhanced nucleation (BEN). In this s ... Full text Cite

Hall effect measurements on boron-doped, highly oriented diamond films grown on silicon via microwave plasma chemical vapor deposition

Journal Article Applied Physics Letters · December 1, 1993 A highly oriented, (100) textured diamond film was grown on a Si substrate, followed by the deposition of an epitaxial boron-doped layer for electrical characterization. Temperature-dependent Hall effect measurements were performed between 180 and 440 K. T ... Full text Cite

Bias assisted etching of diamond in a conventional chemical vapor deposition reactor

Journal Article Applied Physics Letters · December 1, 1993 A novel technique for selectively etching diamond films is presented. This letter describes a technique by which diamond may be etched in a conventional plasma assisted chemical vapor deposition (CVD) reactor at rates comparable to those reported for both ... Full text Cite

Microphotoluminescence and Raman scattering study of defect formation in diamond films

Journal Article Journal of Applied Physics · December 1, 1993 Photoluminescence and Raman spectroscopy are employed to explore the time evolution of defect formation in chemical vapor deposition diamond films for stages of growth spanning nucleation to continuous film formation. Our research is concentrated on three ... Full text Cite

Oriented nucleation and growth of diamond films on β-SiC and Si

Journal Article Applied Physics Letters · December 1, 1993 Oriented diamond nuclei prepared by bias-enhanced microwave plasma chemical vapor deposition on β-SiC and Si were characterized by x-ray texture diffractometry. In both cases, x-ray pole figures reveal an epitaxial relation between the orientation of diamo ... Full text Cite

Textured growth of diamond on silicon via in situ carburization and bias-enhanced nucleation

Journal Article Applied Physics Letters · December 1, 1993 Ordered diamond films have been deposited on single-crystal silicon substrates via an in situ carburization followed by bias-enhanced nucleation. Textured diamond films with greater than 50% of the grains oriented D(100)//Si(100) and D〈110〉//Si〈110〉 were g ... Full text Cite

Fabrication of diamond thin-film thermistors for high-temperature applications

Journal Article Diamond and Related Materials · April 13, 1993 CVD diamond thin-film thermistors have been fabricated in various geometries and at different doping levels in an effort to achieve practical resistance-vs.-temperature characteristics. Typical activation energy values reported for polycrystalline films we ... Full text Cite

Fabrication of diamond thin-film thermistors for high-temperature applications

Journal Article Diamond and Related Materials · April 1, 1993 CVD diamond thin-film thermistors have been fabricated in various geometries and at different doping levels in an effort to achieve practical resistance-vs.-temperature characteristics. Typical activation energy values reported for polycrystalline films we ... Cite

Epitaxial nucleation of diamond on β-SiC via bias-enhanced microwave plasma chemical vapor deposition

Journal Article Diamond and Related Materials · March 31, 1993 Diamond has been successfully nucleated on mirror finish single-crystal β-SiC films via bias-enhanced microwave plasma chemical vapor deposition. Initial scanning electron microscopy indicated that approximately 50% of the diamond grains were oriented rela ... Full text Cite

Diamond and beta -SiC heteroepitaxial interfaces: A theoretical and experimental study.

Journal Article Physical review. B, Condensed matter · March 1993 Full text Cite

Geometric modeling of the diamond-β-SiC heteroepitaxial interface

Journal Article Diamond and Related Materials · March 1, 1993 A theoretical study of the diamond-β-SiC heteroepitaxial interface has been conducted. The interfacial modeling was performed to examine the various combinations of like and unlike interfacial planes between diamond and β-SiC based on a geometric criterion ... Cite

Highly oriented, textured diamond films on silicon via bias-enhanced nucleation and textured growth

Journal Article Journal of Materials Research · January 1, 1993 Highly oriented diamond films were grown on single-crystal silicon substrates. Textured films were first nucleated by a two-step process that involved the conversion of the silicon surface to an epitaxial SiC layer, followed by bias-enhanced nucleation. Th ... Full text Cite

Geometric modeling of the diamond-β-SiC heteroepitaxial interface

Journal Article Diamond and Related Materials · 1993 A theoretical study of the diamond-β-SiC heteroepitaxial interface has been conducted. The interfacial modeling was performed to examine the various combinations of like and unlike interfacial planes between diamond and β-SiC based on a geometric ... Full text Link to item Cite

Epitaxial nucleation of diamond on β-SiC via bias-enhanced microwave plasma chemical vapor deposition

Journal Article Diamond and Related Materials · 1993 Diamond has been successfully nucleated on mirror finish single-crystal β-SiC films via bias-enhanced microwave plasma chemical vapor deposition. Initial scanning electron microscopy indicated that approximately 50% of the diamond grains were oriented ... Full text Link to item Cite

Textured diamond growth on (100) β-SiC via microwave plasma chemical vapor deposition

Journal Article Applied Physics Letters · December 1, 1992 Textured diamond films have been deposited on β-SiC via microwave plasma chemical vapor deposition preceded by an in situ bias pretreatment that enhances nucleation. Approximately 50% of the initial diamond nuclei appear to be aligned with the C(001) plane ... Full text Cite

Electrical conductivity and photoluminescence of diamond films grown by downstream microwave plasma CVD

Journal Article Journal of Electronic Materials · 1992 Electrical conductivity measurements and photoluminescence (PL) were used to study the effects that sample distance from the plasma during growth has on the carrier transport properties of undoped CVD diamond. The films were grown by downstream microwave p ... Cite

In situ growth rate measurement and nucleation enhancement for microwave plasma CVD of diamond

Journal Article Journal of Materials Research · January 1, 1992 Laser reflection interferometry (LRI) has been shown to be a useful in situ technique for measuring growth rate of diamond during microwave plasma chemical vapor deposition (MPCVD). Current alternatives to LRI usually involve ex situ analysis such as cross ... Full text Cite

Observation of surface modification and nucleation during deposition of diamond on silicon by scanning tunneling microscopy

Journal Article Journal of Applied Physics · December 1, 1991 The surface topography of silicon substrates after the initial stages of diamond growth, by microwave plasma enhanced chemical vapor deposition, has been observed by scanning tunneling microscopy. The initial surfaces were polished with diamond paste befor ... Full text Cite

Growth and Characterization of Diamond Films on Nondiamond Substrates for Electronic Applications

Journal Article Proceedings of the IEEE · January 1, 1991 This review concentrates on recent advances in the chemical vapor deposition (CVD) and characterization of diamond films on nondiamond substrates. Major growth techniques including hot filament CVD, microwave, RF or dc plasma enhanced CVD, and combustion f ... Full text Cite